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28460-01-7 - Diethyl methylthiomethylphosphonate, 97% - Methylthiomethylphosphonic acid diethyl ester - L00579 - Alfa Aesar

L00579 Diethyl methylthiomethylphosphonate, 97%

Número CAS
28460-01-7
Nombre Alternativo
Methylthiomethylphosphonic acid diethyl ester

Tamaño Precio ($) Cantidad Disponibilidad
5g 60,30
25g 239,00
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Diethyl methylthiomethylphosphonate, 97%

MDL
MFCD00015131

Propiedades químicas

Fórmula
C6H15O3PS
Peso molecular
198.22
Punto de ebullición
70-72°/0.2mm
Punto de inflamabilidad
101°(213°F)
Densidad
1.130
Índice de refracción
1.4660
Solubilidad
It is insoluble in water.

Aplicaciones

Diethyl methylthiomethylphosphonate, is used as an important raw material and intermediate used in organic Synthesis, pharmaceuticals, agrochemicals and dyestuff. Diethyl(methylthiomethyl) phosphonate is a reactant for the synthesis of (+)-minfiensine via organocatalytic Diels-Alder/amine cyclization and 6-exo-dig radical cyclization. It is used in the preparation of fused nitrogen, sulfur, and phosphorus containing heterocyclic and relevant difurylpyridazine phosphonates with antimicrobial activity. It is also used as a reactant used in the preparation of fused heterocyclic.

Notas

Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Keep away from oxidizing agents. Stable under recommended storage conditions.

Referencias documentales

EJ Corey.; JI Shulman. Application of lithium reagents from (1-methylthio) alkylphosphonate esters to the synthesis of ketones. The Journal of Organic Chemistry. 197035,(3) , 777-780.

J Motoyoshiya.; Y Hongo.; H Tanaka. A Convenient Synthesis of 1, 4-Diketones. Synthetic Communications. . 199121,(8-9) , 997-1000.

Indicaciones de peligro y de precaución del GHS

Indicaciones de peligro (UE): H315-H319

Causes skin irritation. Causes serious eye irritation.

Indicaciones de precaución: P280-P264-P305+P351+P338-P362-P321-P332+P313-P337+P313-P302+P352

Wear protective gloves/protective clothing/eye protection/face protection. Wash thoroughly after handling. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Take off contaminated clothing and wash before reuse. Specific treatment (see label). If skin irritation occurs: Get medical advice/attention. If eye irritation persists: IF ON SKIN: Wash with plenty of soap and water.

Otras referencias

Beilstein
1705833
Código de tarifa arancelaria unificado
2931.90
TSCA
No

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