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437-17-2 - Triphenylcarbenium hexafluorophosphate, 98% - Tritylium hexafluorophosphate - Trityl hexafluorophosphate - L03140 - Alfa Aesar

L03140 Triphenylcarbenium hexafluorophosphate, 98%

Número CAS
437-17-2
Nombre Alternativo
Tritylium hexafluorophosphate
Trityl hexafluorophosphate

Tamaño Precio ($) Cantidad Disponibilidad
10g 60,30
50g 258,00
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Triphenylcarbenium hexafluorophosphate, 98%

MDL
MFCD00013121
EINECS
207-112-0

Propiedades químicas

Fórmula
C19H15F6P
Peso molecular
388.29
Punto de fusión
ca 160° dec.
Sensibilidad
Moisture Sensitive
Solubilidad
Soluble in water. (27 g/L) at 25°C.

Aplicaciones

Triphenylcarbenium hexafluorophosphate is a reagent involved in Si-H and Si-Si bond activation at Pt of neutral and cationic silyl Pt bisphosphine complexes. It is used in investigations of interactions with chromium acetylacetonate nitride mononuclear complexes. It is used in double ring-opening polyaddition of spiro orthoesters. It is used as reagent in Synthesis of "push-pull" tropylium-fused aminoporphyrazine, Preparation of cycloheptatrienyl and tropylium calix[4]arenes, Synthesis of palladacycles containing chiral rhenium half-sandwich complex for use as a catalyst.

Notas

Moisture Sensitive. Store at 4°C. Store away from oxidizing agents and strong bases. Incompatible with heat and water.

Referencias documentales

Jan Voigt; Thomas Braun. Si-H and Si-Si activation at Pt: synthesis and reactivity of neutral and cationic silyl complexes.Dalton Transactions.2011, 40 (47), 12699-12704.

Indicaciones de peligro y de precaución del GHS

Indicaciones de peligro (UE): H314-H318

Causes severe skin burns and eye damage. Causes serious eye damage.

Indicaciones de precaución: P280-P303+P361+P353-P305+P351+P338-P301+P330+P331-P310a

Wear protective gloves/protective clothing/eye protection/face protection. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. Immediately call a POISON CENTER/doctor

Otras referencias

Beilstein
4344297
Clase de peligro
8
Grupo de embalaje
II
Código de tarifa arancelaria unificado
2942.00
TSCA
Yes

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