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175136-62-6 - Tris[3,5-bis(trifluoromethyl)phenyl]phosphine, 94% - L06941 - Alfa Aesar

L06941 Tris[3,5-bis(trifluoromethyl)phenyl]phosphine, 94%

Número CAS
175136-62-6
Nombre Alternativo

Tamaño Precio ($) Cantidad Disponibilidad
250mg 43,70
1g 122,00
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Tris[3,5-bis(trifluoromethyl)phenyl]phosphine, 94%

MDL
MFCD00042428

Propiedades químicas

Fórmula
C24H9F18P
Peso molecular
670.28
Punto de fusión
98-102°
Punto de ebullición
128-130°/0.5mm
Solubilidad
Insoluble in water.

Aplicaciones

Tris[3,5-bis(trifluoromethyl)phenyl]phosphine is used as ligands which is useful as catalysts in various reactions.

Notas

Stable under recommended storage conditions. Incompatible with oxidizing agents.

Referencias documentales

Shin-ichiro Fujita; Shinya Fujisawa; Bhalchandra M.Bhanage; Masahiko Arai. Rhodium-tris(3,5-bis(trifluoromethyl)phenyl)phosphine catalyzed hydroformylation of dienes to dialdehydes in supercritical carbon dioxide with high activity. Tetrahedron Letters. 2004, 45,(6), 1307-1310.

 

Tatsuo Ishiyama; Hironori Isou; Takao Kikuchi; Norio Miyaura. Ortho-C-H borylation of benzoate esters with bis(pinacolato)diboron catalyzed by iridium-phosphine complexes. Chem. Commun. 2010, 46,(1), 159-161.

In a study of coupling reactions in supercritical CO2, catalyzed by Tris(dibenzyl­ideneacetone)­dipalladium(0)­, 12760, this ligand was among the best tried in both the Stille and Heck reactions, giving much superior results to e.g. triphenyl- or tri(o-tolyl)phosphine: Chem. Commun., 1397 (1998). See also Tri(2-furyl)­phosphine, L13329, Tris(pentafluorophenyl)­phosphine, L02748

Indicaciones de peligro y de precaución del GHS

Indicaciones de peligro (UE): H315-H319-H335

Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.

Indicaciones de precaución: P261-P280a-P305+P351+P338-P304+P340-P405-P501a

Avoid breathing dust/fume/gas/mist/vapours/spray. Wear protective gloves and eye/face protection. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

Otras referencias

Beilstein
6556841
Código de tarifa arancelaria unificado
2931.39
TSCA
No

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