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814-68-6 - Acryloyl chloride, 96%, stab. with 400ppm phenothiazine - Propenoyl chloride - L10363 - Alfa Aesar

L10363 Acryloyl chloride, 96%, stab. with 400ppm phenothiazine

Número CAS
814-68-6
Nombre Alternativo
Propenoyl chloride

Tamaño Precio ($) Cantidad Disponibilidad
10g 37,20
50g 57,90
250g 212,00
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Acryloyl chloride, 96%, stab. with 400ppm phenothiazine

MDL
MFCD00000731
EINECS
212-399-0

Propiedades químicas

Fórmula
C3H3ClO
Peso molecular
90.51
Punto de ebullición
74-76°
Punto de inflamabilidad
-4°(24°F)
Densidad
1.114
Índice de refracción
1.4350
Sensibilidad
Moisture & Light Sensitive
Solubilidad
Miscible with water.

Aplicaciones

Acryloyl chloride is used in the production of plastics. It plays an important role in the preparation of acrylate monomers and polymers. It also acts as a substrate for cross-metathesis. Further, it is utilized in organic synthesis for the introduction of acrylic groups into other compounds.

Notas

Moisture and light sensitive. Keep the container tightly closed in a dry and well-ventilated place. Incompatible with alcohols, oxidizing agents, strong bases and polymerizing initiators.

Referencias documentales

Warneke, J.; Plaumann, M.; Wang, Z.; Böhler, E.; Kemken, D.; Kelm, S.; Leibfritz, D.; Azov, V. A. New insights into the old reaction between acryloyl chlorides and pyridine. Tetrahedron Lett. 2015, 56 (9), 1124-1127.

Lee, P. W.; Scrape, P. G.; Butler, L. G.; Lee, Y. P. Two HCl-Elimination Channels and Two CO-Formation Channels Detected with Time-Resolved Infrared Emission upon Photolysis of Acryloyl Chloride [CH2CHC(O)Cl] at 193 nm. J. Phys. Chem. A 2015, 119 (28), 7293-7304.

Indicaciones de peligro y de precaución del GHS

Indicaciones de peligro (UE): H225-H330-H302-H314-H318

Highly flammable liquid and vapour. Fatal if inhaled. Harmful if swallowed. Causes severe skin burns and eye damage. Causes serious eye damage.

Indicaciones de precaución: P210-P260-P284-P303+P361+P353-P304+P340-P305+P351+P338-P320-P330-P405-P501a

Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Do not breathe dust/fume/gas/mist/vapours/spray. Wear respiratory protection. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Specific treatment is urgent (see label). Rinse mouth. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

Otras referencias

Beilstein
635744
Clase de peligro
6.1
Grupo de embalaje
I
Código de tarifa arancelaria unificado
2916.19
TSCA
Yes
RTECS
AT7350000

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