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L13909 Isopentyl nitrite, 97%, stab. with 0.2% anhyd. sodium carbonate

Número CAS
Nombre Alternativo
Amyl nitrite
Isoamyl nitrite

Stock No. Tamaño Precio ($) Cantidad Disponibilidad
L13909-AC 25ml 22,40
L13909-AE 100ml 40,00
L13909-AP 500ml 121,00
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Isopentyl nitrite, 97%, stab. with 0.2% anhyd. sodium carbonate


Propiedades químicas

Peso molecular
Punto de ebullición
Punto de inflamabilidad
Índice de refracción
Storage & Sensitivity
Keep Cold. Air Sensitive. Light Sensitive.
Miscible with methanol, chloroform and ether. Slightly miscible with water.


Isopentyl nitrite is used in the conversion of 2,6-disubstituted phenols to diphenoquinones and aminophenols to quinone diazides. It acts as an oxidant and nitrosating agent. It finds application in aromatic arylation, deamination of arylamines using tetrahydrofuran as a hydrogen donor. It is also useful for the preparation of benzyne using anthranilic acid. It is an antihypertensive and vasodilator to treat heart diseases such as angina and an antidote for cyanide poisoning. Further, it is used as a solvent and cleaning agent for a printed circuit board. In addition to this, it is considered to be a replacement for freon.


Air, moisture and light sensitive. Store in a cool place. Keep the container tightly closed in a dry and well-ventilated place. Incompatible with oxidizing agents and alcohol.

Referencias documentales

Widely used in non-aqueous nitrosation and diazotization reactions.

For aromatic arylation as an alternative to the Gomberg reaction, see: J. Chem. Soc., 4257 (1962). For deamination of arylamines using THF as a hydrogen donor, see: J. Chem. Soc., Perkin 1, 541 (1973).

For use in the generation of benzyne from anthranilic acid, see: J. Org. Chem., 38, 3462 (1973).

ɑ-Amino esters are converted to ɑ-diazo esters: Tetrahedron, 31, 227 (1975).

For other reactions of alkyl nitrites, see Isobutyl­ nitrite, L05259 , and tert-Butyl­ nitrite, L16135 .

Liu, Z.; Zhu, S.; Li, Y.; Li, Y.; Shi, P.; Huang, Z.; Huang, X. Preparation of graphene/poly(2-hydroxyethyl acrylate) nanohybrid materials via an ambient temperature “grafting-from” strategy. Polym. Chem. 2015, 6 (2), 311-321.

Wang, Y.; Meng, L.; Fan, L.; Wu, G.; Ma, L.; Huang, Y. Preparation and properties of carbon nanotube/carbon fiber hybrid reinforcement by a two-step aryl diazonium reaction. RSC Adv. 2015, 5 (55), 44492-44498.

Indicaciones de peligro y de precaución del GHS

Indicaciones de peligro (UE): H225-H302-H331

Highly flammable liquid and vapour. Harmful if swallowed. Toxic if inhaled.

Indicaciones de precaución: P210-P261-P280a-P303+P361+P353-P405-P501a

Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Avoid breathing dust/fume/gas/mist/vapours/spray. Wear protective gloves and eye/face protection. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

Otras referencias

Clase de peligro
Grupo de embalaje
Código de tarifa arancelaria unificado


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