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20039-37-6 - Pyridinium dichromate, 98% - PDC - L15132 - Alfa Aesar

L15132 Pyridinium dichromate, 98%

Número CAS
20039-37-6
Nombre Alternativo
PDC

Tamaño Precio ($) Cantidad Disponibilidad
25g 27,00
100g 57,40
500g 182,00
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Pyridinium dichromate, 98%

MDL
MFCD00013105
EINECS
243-478-8

Propiedades químicas

Fórmula
C10H12Cr2N2O7
Peso molecular
376.21
Punto de fusión
ca 145-147°
Sensibilidad
Hygroscopic
Solubilidad
Soluble in water, dimethyl formamide, dimethyl sulfoxide and acetonitrile. Slightly soluble in dichloromethane, chloroform and acetone. Insoluble in hexane, ether and ethyl acetate.

Aplicaciones

Pyridinium dichromate acts as a strong oxidizing agent used in the conversion of primary alcohols and secondary alcohols to aldehydes and ketones respectively. It plays an important role in the oxidation of unsaturated tertiary alcohols, silyl ethers, the carbon-boron bond, and oximes. Further, it is used in the conversion of acetals to esters and didehydroketones to enones in the presence of tert-butyl hydroperoxide.

Notas

Hygroscopic. Incompatible withorganic materials and powdered metals.

Referencias documentales

Selective oxidant which can be used in dichloromethane to convert primary alcohols to aldehydes: Tetrahedron Lett., 399 (1979). Can also be used catalytically in combination with Sodium percarbonate, A16045, as co-oxidant for conversion of allylic and benzylic alcohols to aldehydes under phase-transfer conditions: Tetrahedron Lett., 35, 1989 (1994). Under the same conditions, ɑ-functionalized benzylic alcohols undergo oxidative cleavage: Synth. Commun., 25, 2051 (1995).

Matsunaga, K.; Hirajima, H.; Kishida, A.; Takatori, K.; Nagaoka, H. Novel PDC catalyzed oxidative rearrangement of tertiary allylic alcohols to beta-substituted enones. Tetrahedron Lett. 2015, 56 (43), 5941-5944.

Ghosh, A.; Saha, R.; Mukherjee, K.; Ghosh, S. K.; Sar, P.; Malik, S.; Saha, B. Choice of suitable micellar catalyst for 2,2'-bipyridine-promoted chromic acid oxidation of glycerol to glyceraldehyde in aqueous media at room temperature. Res. Chem. Intermed. 2015, 41 (5), 3057-3078.

Indicaciones de peligro y de precaución del GHS

Indicaciones de peligro (UE): H272-H314-H317-H351

May intensify fire; oxidizer. Causes severe skin burns and eye damage. May cause an allergic skin reaction. Suspected of causing cancer.

Indicaciones de precaución: P221-P210v-P303+P361+P353-P305+P351+P338-P405-P501a

Take any precaution to avoid mixing with combustibles. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

Otras referencias

Clase de peligro
5.1
Grupo de embalaje
II
Código de tarifa arancelaria unificado
2933.39
TSCA
Yes

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