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87199-15-3 - 3-(Hydroxymethyl)benzeneboronic acid, 98% - 3-(Hydroxymethyl)phenylboronic acid - L15193 - Alfa Aesar

L15193 3-(Hydroxymethyl)benzeneboronic acid, 98%

Número CAS
87199-15-3
Nombre Alternativo
3-(Hydroxymethyl)phenylboronic acid

Tamaño Precio ($) Cantidad Disponibilidad
1g 44,20
5g 117,00
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3-(Hydroxymethyl)benzeneboronic acid, 98%

MDL
MFCD01317846

Propiedades químicas

Fórmula
C7H9BO3
Peso molecular
151.96
Punto de fusión
93-98°
Solubilidad
Soluble in water.

Aplicaciones

Reactant used for copper-mediated trifluoromethylation, copper-catalyzed transformations from arylboronic acids in water, Mitsunobu, Suzuki, and amidation reactions with hydroxyphenylamino bromopyrazinecarboxylate. Reactant involved in the synthesis of biologically active molecules including Mycobacterium tuberculosis H37Rv chorismate mutase inhibitors via Suzuki coupling reactions, HIV protease inhibitors with antiviral activity against drug-resistant viruses, Pyrrole derivatives for use as PDE4B inhibitors.

Notas

Store in cool. Keep container tightly closed in a dry and well-ventilated place. Store away from oxidizing agent.

Referencias documentales

Cheng-Pan Zhang et. al. Copper-mediated trifluoromethylation of arylboronic acids by trifluoromethyl sulfonium salts.. ChemicalCommunications.2011, 47,(33), 9516-9518.

Haijun Yang et. al. General copper-catalyzed transformations of functional groups from arylboronic acids in water. Chemistry: A European Journal.2011, 17, (20), 5652-5660.

Indicaciones de peligro y de precaución del GHS

Indicaciones de peligro (UE): H315-H319-H335

Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.

Indicaciones de precaución: P261-P280a-P305+P351+P338-P304+P340-P405-P501a

Avoid breathing dust/fume/gas/mist/vapours/spray. Wear protective gloves and eye/face protection. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

Otras referencias

Beilstein
8832019
Código de tarifa arancelaria unificado
2931.90
TSCA
No

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