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133407-38-2 - (R)-(+)-N-Methoxymethyl-N-(trimethylsilyl)methyl-1-phenylethylamine, tech. 85% - L19413 - Alfa Aesar

L19413 (R)-(+)-N-Methoxymethyl-N-(trimethylsilyl)methyl-1-phenylethylamine, tech. 85%

Número CAS
133407-38-2
Nombre Alternativo

Tamaño Precio ($) Cantidad Disponibilidad
1g 63,36
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(R)-(+)-N-Methoxymethyl-N-(trimethylsilyl)methyl-1-phenylethylamine, tech. 85%

MDL
MFCD06798959

Propiedades químicas

Fórmula
C14H25NOSi
Peso molecular
251.45
Punto de ebullición
82-84°/0.2mm
Densidad
0.926
Índice de refracción
1.4930
Sensibilidad
Moisture Sensitive
Solubilidad
Not miscible or difficult to mix in water.

Aplicaciones

(R)-(+)-N-Methoxymethyl-N-(trimethylsilyl)methyl-1-phenylethylamine ligand is commonly used in the synthesis of organometallic catalysts and for many applications, such as asymmetric hydrogenation, asymmetric hydroboration, coupling reactions, addition reactions and reductions reactions.

Notas

Store under inert gas. It is sensitive to moisture. Store in a cool, dry conditions in well sealed containers. Incompatible with oxidizing agents.

Referencias documentales

Andrew H. Fray.; A. I. Meyers. Single and Double Diastereoselection in Azomethine Ylide Cycloaddition Reactions with Unsaturated Chiral Bicyclic Lactams. J. Org. Chem. 1996, 61 (10), 3362-3374.

The azomethine ylide, from the reaction with TFA in DCM, showed high facial selectivity in additions to chiral unsaturated bicyclic lactams: J. Org. Chem., 61, 3362 (1996).

Indicaciones de peligro y de precaución del GHS

Indicaciones de peligro (UE): H315-H319-H335

Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.

Indicaciones de precaución: P261-P280-P305+P351+P338-P304+P340-P362-P312-P321-P405-P403+P233-P501a

Avoid breathing dust/fume/gas/mist/vapours/spray. Wear protective gloves/protective clothing/eye protection/face protection. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Take off contaminated clothing and wash before reuse. Call a POISON CENTER or doctor/physician if you feel unwell. Specific treatment (see label). Store locked up. Store in a well-ventilated place. Keep container tightly closed. Dispose of contents/container in accordance with local/regional/national/international regulations.

Otras referencias

Beilstein
4745464
Código de tarifa arancelaria unificado
2931.90
TSCA
No

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