(R)-(+)-N-Methoxymethyl-N-(trimethylsilyl)methyl-1-phenylethylamine ligand is commonly used in the synthesis of organometallic catalysts and for many applications, such as asymmetric hydrogenation, asymmetric hydroboration, coupling reactions, addition reactions and reductions reactions.
Andrew H. Fray.; A. I. Meyers. Single and Double Diastereoselection in Azomethine Ylide Cycloaddition Reactions with Unsaturated Chiral Bicyclic Lactams. J. Org. Chem. 1996, 61 (10), 3362-3374.
The azomethine ylide, from the reaction with TFA in DCM, showed high facial selectivity in additions to chiral unsaturated bicyclic lactams: J. Org. Chem., 61, 3362 (1996).
Indicaciones de peligro (UE): H315-H319-H335
Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.
Indicaciones de precaución: P260-P201-P280g-P304+P340-P405-P501a
Do not breathe dust/fume/gas/mist/vapours/spray. Obtain special instructions before use. Wear protective gloves. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.