Consentement d'utilisation des Cookies

J'accepte Notre site sauvegarde des traceurs textes (cookies) sur votre appareil afin de vous garantir de meilleurs contenus et à des fins de collectes statistiques.Vous pouvez désactiver l'usage des cookies en changeant les paramètres de votre navigateur. En poursuivant votre navigation sur notre site sans changer vos paramètres de navigateur vous nous accordez la permission de conserver des informations sur votre appareil.

10025-87-3 - Phosphorus(V) oxychloride, 99% - Phosphorus(V) trichloride oxide - Phosphoryl chloride - 10525 - Alfa Aesar

10525 Phosphorus(V) oxychloride, 99%

Numéro CAS
10025-87-3
Synonymes
Phosphorus(V) trichloride oxide
Phosphoryl chloride

Dimensions Prix ($) Quantité Disponibilité
250g 31,86
1kg 81,09
Ajouter au panier Ajouter au devis en vrac Afficher l'article

Phosphorus(V) oxychloride, 99%

MDL
MFCD00011443
EINECS
233-046-7

Propriétés chimiques

Formule
Cl3OP
Poids formulaire
153.33
Forme
Liquid
Point de fusion
1.25°
Point d'ébullition
105.8°
Densité
1.645
Indice de réfraction
1.460
Sensibilité
Moisture Sensitive
Solubilité
Phosphorus(V) oxychloride is soluble in many organic solvents.

Applications

Phosphorus(V) oxychloride is widely used as a dehydrating agent and a chlorinating agent. Useful for the conversion of amide to nitriles, Bischler-Napieralski reaction, Vilsmeier Haak reaction, and other reactions producing commercially important intermediates. Acts a source of liquid phosphorus in semiconductor industry. Manufacture of trialkyl phosphate esters and triarylphosphate esters, including commercially popular tricresyl phosphate,which is useful as a plasticizer, flame retardant, gasoline additive, hydrolytic fluid, etc.

Notes

On exposure to moisture, it decomposes to produce phosphoric acid and fumes of hydrogen chloride gas. It is stored away from incompatible such as reducing agents, metals, acids and alkalis.

Références bibliographiques

Farzipour, S.; Saeedi, M.; Mahdavi, M.; Yavari, H.; Mirzahekmati, M.; Ghaemi, N.; Foroumadi, A.; Shafiee, A. An Efficient Reagent for the Transformation of 2-Amino benzamides into Quinazolin-4(3h)-one Derivatives. Syn. Commun. 2014, 44, 481-487.

Brenek, S. J.; am Ende, D. J.; Clifford, P. J. Phosphorus Oxychloride and Acetone:? An Incompatibility Investigation Using ARC. Org. Proc. Res. Dev. 2000, 4 (6), 585-586.

Mentions de danger et de prudence du SGH

Mentions de danger (UE): H330-H302-H372-H314

Fatal if inhaled. Harmful if swallowed. Causes damage to organs through prolonged or repeated exposure. Causes severe skin burns and eye damage.

Mentions de prudence: P260-P284-P303+P361+P353-P304+P340-P305+P351+P338-P320-P330-P301+P330+P331-P405-P501a

Do not breathe dust/fume/gas/mist/vapours/spray. Wear respiratory protection. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Specific treatment is urgent (see label). Rinse mouth. IF SWALLOWED: Do NOT induce vomiting. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

Autres références

Merck
14,7349
Classe de danger
6.1
Groupe d'emballage
I
Code tarifaire harmonisé
2812.10
TSCA
Yes
RTECS
TH4897000

Recommandé

Consulté récemment

Produits chimiques

Sciences de la vie

Métaux et matériaux

Catalyseurs

Analytique et matériel de laboratoire