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13778-31-9 - Copper(II) nitrate hydrate, Puratronic®, 99.999% (metals basis) - 10699 - Alfa Aesar

10699 Copper(II) nitrate hydrate, Puratronic®, 99.999% (metals basis)

Numéro CAS
13778-31-9
Synonymes

Dimensions Prix ($) Quantité Disponibilité
5g 23,70
25g 60,40
100g 187,00
500g 567,00
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Copper(II) nitrate hydrate, Puratronic®, 99.999% (metals basis)

MDL
MFCD00149669
EINECS
221-838-5

Propriétés chimiques

Formule
CuN2O6•xH2O
Poids formulaire
187.55(anhy)
Forme
Crystalline Aggregates
Sensibilité
Hygroscopic
Solubilité
Soluble in ethanol and water. Insoluble in ethyl acetate.

Applications

It serves as a catalyst for oxidative coupling of 2,6-dimethylphenol, resulting in an important engineering polymer material. Also used in textiles and polishing agents for other metals. It is a precursor for copper oxide, which finds use as a catalyst for many organic transformations. Menke conditions employ copper nitrate for aromatic nitrations. Claycop reagent, the hydrated copper nitrate deposited on clay, finds use in many organic reactions, for example, oxidation of dithioacetals to carbonyls and thiols to disulfides.

Notes

Hygroscopic. On heating, it forms basic copper nitrate containing hydroxy anions, and on further heating, it forms cupric oxide liberating nitrogen dioxide and oxygen.

Références bibliographiques

Gascon, J.; Aguado, S.; Kapteijn, F. Manufacture of Dense Coatings of Cu3(BTC)2 (HKUST-1) on alpha-Alumina. Micropor. Mesopor. Mat. 2008, 113 (1-3), 132-138.

El-Shall, M. S.; Abdelsayed, V.; Khder, A. E. R. S.; Hassan, H. M. A.; El-Kaderi, H. M.; Reich, T. E. Metallic and Bimetallic Nanocatalysts Incorporated into Highly Porous Coordination Polymer MIL-101. J. Mater. Chem. 2009, 19, 7625-7631.

Mentions de danger et de prudence du SGH

Mentions de danger (UE): H272-H314-H318-H302

May intensify fire; oxidizer. Causes severe skin burns and eye damage. Causes serious eye damage. Harmful if swallowed.

Mentions de prudence: P221-P210-P260-P220-P280-P303+P361+P353-P305+P351+P338-P301+P330+P331-P405-P501a

Take any precaution to avoid mixing with combustibles. Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Do not breathe dust/fume/gas/mist/vapours/spray. Keep/Store away from clothing/combustible materials. Wear protective gloves/protective clothing/eye protection/face protection. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

Autres références

Merck
14,2643
Classe de danger
5.1
Groupe d'emballage
III
Code tarifaire harmonisé
2834.29
TSCA
Yes
RTECS
GL7875000

Recommandé

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    Cobalt(II) nitrate hexahydrate, Puratronic®, 99.999% (metals basis)
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    Nickel(II) nitrate hexahydrate, Puratronic®, 99.9985% (metals basis)
  • 11330

    Cerium(III) nitrate hexahydrate, REacton®, 99.99% (REO)
  • 12313

    Zinc nitrate hexahydrate, 99% (metals basis)
  • 43182

    Chromium(III) nitrate nonahydrate, 99.99% min (metals basis)

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