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14996-61-3 - Iridium(III) chloride hydrate, 99.8% (metals basis) - 11030 - Alfa Aesar

11030 Iridium(III) chloride hydrate, 99.8% (metals basis)

Numéro CAS
14996-61-3
Synonymes

Dimensions Prix ($) Quantité Disponibilité
1g 99,35
5g 337,04
25g 1323,20
50g Prix sur demande. Cliquez sur le Bouton "Ajouter au devis en vrac" et spécifiez les conditionnements et quantités.
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Iridium(III) chloride hydrate, 99.8% (metals basis)

MDL
MFCD00149750
EINECS
233-044-6

Propriétés chimiques

Formule
IrCl3•xH2O
Poids formulaire
298.56(anhy)
Forme
Crystalline
Solubilité
Soluble in water and alcohol.

Applications

Iridium(III) chloride hydrate is used to prepare other iridium compounds. It finds use as a catalyst for oxidation in presence of cerium(IV) and in the the manufacture of electrodes. Iridium(III) chloride is used in iridium electroplating, in making the standard meter bar of Paris and crucibles. It is used for high temperature electrical contacts, as hardening agent, in tipping pens and compass bearings and Pt/Ir spark plugs. It is used for medical, surgical or other patient oriented applications, MMO (mixed metal oxide) titanium electrode coatings and as a starting material for heterogeneous catalysts.

Notes

Hygroscopic and Incompatible with strong oxidants.

Références bibliographiques

Botelho, M. B. S.; Hernandez, J. M. F.; Queiroz, T. B.; Eckert, H.; Cola, L.; Camargo, A. S. S. Iridium(iii)-surfactant complex immobilized in mesoporous silica via templated synthesis: a new route to optical materials. J. Mater. Chem. 2011, 21, 8829-8834.

Tandon, P. K. ; Sahgal, S.; Srivastava, M.; Singh, S. B. Catalysis by Ir(III), Rh(III) and Pd(II) metal ions in the oxidation of organic compounds with H2O2. Appl. Organomet. Chem. 2007, 21 (3), 135-138.

Tandon, P. K.; Sahgal, S.; Gayatri; Purwar, M.; Dhusia, M. Oxidation of Ketones by Cerium(IV) in Presence of Iridium(III) Chloride. J. Mol. Catal. A: Chem. 2006, 250 (1-2), 203-209.

Tandon, P. K.; Singh, A. K.; Sahgal, S.; Kumar, S. Oxidation of Cyclic Alcohols by Cerium(IV) in Acidic Medium in the Presence of Iridium(III) chloride. J. Mol. Catal. A: Chem. 2008, 282 (1-2), 136-143.

Mentions de danger et de prudence du SGH

Mentions de danger (UE): H314-H318

Causes severe skin burns and eye damage. Causes serious eye damage.

Mentions de prudence: P260-P280-P303+P361+P353-P305+P351+P338-P301+P330+P331-P304+P340-P310-P363-P405-P501a

Do not breathe dust/fume/gas/mist/vapours/spray. Wear protective gloves/protective clothing/eye protection/face protection. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Immediately call a POISON CENTER or doctor/physician. Wash contaminated clothing before reuse. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

Autres références

Merck
14,5088
Classe de danger
8
Groupe d'emballage
II
Code tarifaire harmonisé
2843.90
TSCA
Yes

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Consulté récemment

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Analytique et matériel de laboratoire