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14898-67-0 - Ruthenium(III) chloride hydrate, 99.9% (PGM basis), Ru 38% min - 11043 - Alfa Aesar

11043 Ruthenium(III) chloride hydrate, 99.9% (PGM basis), Ru 38% min

Numéro CAS
14898-67-0
Synonymes

Dimensions Prix ($) Quantité Disponibilité
2g 70,84
10g 244,45
50g 927,00
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Ruthenium(III) chloride hydrate, 99.9% (PGM basis), Ru 38% min

MDL
MFCD00149844
EINECS
233-167-5

Propriétés chimiques

Formule
Cl3Ru•xH2O
Poids formulaire
207.43(anhy)
Forme
Crystalline Soluble
Point de fusion
100°dec
Sensibilité
Hygroscopic
Solubilité
Very soluble in water. Soluble in alcohol, acetone.

Applications

Oxidation.Ruthenium(III) chloride hydrate is used as a catalyst for alkyne functionalization and oxidation reactions. It is used as key raw materials for the preparation of various ruthenium-based catalysts, including Grubbs’ catalysts. It is utilized in the preparation of nanoparticulate ruthenium-aluminum oxyhydroxide catalyst, which is efficient for dehydrogenation of alcohols to the corresponding aldehydes. It is also involved in the synthesis of 2-ethyl-3-methylquinolines from primary aromatic amines and triallylamine.

Notes

Hygroscopic. Incompatible with zinc.

Références bibliographiques

Wang, J.; Zhao, J.; Osterloh, F. E. Photochemical charge transfer observed in nanoscale hydrogen evolving photocatalysts using surface photovoltage spectroscopy. Energy Environ. Sci. 2015, 8 (10), 2970-2976.

Nazarov, A. A.; Meier, S. M.; Zava, O.; Nosova, Y. N.; Milaeva, E. R.; Hartinger, C. G.; Dyson, P. J. Protein ruthenation and DNA alkylation: chlorambucil-functionalized RAPTA complexes and their anticancer activity. Dalton Trans. 2015, 44 (8), 3614-3623.

Mentions de danger et de prudence du SGH

Mentions de danger (UE): H314-H318-H290-H302-H412

Causes severe skin burns and eye damage. Causes serious eye damage. May be corrosive to metals. Harmful if swallowed. Harmful to aquatic life with long lasting effects.

Mentions de prudence: P260-P273-P280-P303+P361+P353-P305+P351+P338-P301+P330+P331-P304+P340-P310-P405-P501a

Do not breathe dust/fume/gas/mist/vapours/spray. Avoid release to the environment. Wear protective gloves/protective clothing/eye protection/face protection. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Immediately call a POISON CENTER or doctor/physician. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

Autres références

Merck
14,8302
Classe de danger
8
Groupe d'emballage
III
Code tarifaire harmonisé
2843.90
TSCA
Yes
RTECS
VM2650000

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