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10361-82-7 - Samarium(III) chloride hydrate, REacton®, 99.9% (REO) - 11231 - Alfa Aesar

11231 Samarium(III) chloride hydrate, REacton®, 99.9% (REO)

Numéro CAS
10361-82-7
Synonymes

Dimensions Prix ($) Quantité Disponibilité
25g 50,88
100g 172,01
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Samarium(III) chloride hydrate, REacton®, 99.9% (REO)

MDL
MFCD00011235
EINECS
233-797-0

Propriétés chimiques

Formule
SmCl3•xH2O
Poids formulaire
256.71(anhy)
Forme
Crystalline Aggregates
Point de fusion
110° -5H{2}O
Sensibilité
Hygroscopic
Solubilité
Soluble in water and pyridine.

Applications

Samarium(III) chloride hydrate is used for the preparation of samarium metal, which finds use as magnets. It is combined with sodium chloride to get a low melting point eutectic mixture. Further, it serves as a precursor for the preparation of other samarium salts and bis(pentamethylcyclopentadienyl)alkylsamarium(III) complexes. In addition, it serves as a catalyst for hydrogenation and hydrosilylation of alkenes.

Notes

Hygroscopic. Incompatible with strong oxidizing agents.

Références bibliographiques

Muneer, I.; Farrukh, M. A.; Javaid, S.; Shahid, M.; Khaleeq-ur-Rahman, M. Synthesis of Gd2O3/Sm2O3 nanocomposite via sonication and hydrothermal methods and its optical properties. Superlattices Microstruct. 2015, 77, 256-266.

Mueller, R.; Zhang, S.; Klink, M.; Bäumer, M.; Vasenkov, S. The origin of a large apparent tortuosity factor for the Knudsen diffusion inside monoliths of a samaria-alumina aerogel catalyst: a diffusion NMR study. Phys. Chem. Chem. Phys. 2015, 17 (41), 27481-27487.

Mentions de danger et de prudence du SGH

Mentions de danger (UE): H315-H319-H335-H303

Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation. May be harmful if swallowed.

Mentions de prudence: P261-P280-P305+P351+P338-P304+P340-P362-P312-P321-P405-P403+P233-P501a

Avoid breathing dust/fume/gas/mist/vapours/spray. Wear protective gloves/protective clothing/eye protection/face protection. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Take off contaminated clothing and wash before reuse. Call a POISON CENTER or doctor/physician if you feel unwell. Specific treatment (see label). Store locked up. Store in a well-ventilated place. Keep container tightly closed. Dispose of contents/container in accordance with local/regional/national/international regulations.

Autres références

Merck
14,8347
Code tarifaire harmonisé
2846.90
TSCA
Yes

Recommandé

  • 11237

    Praseodymium(III) chloride hydrate, REacton®, 99.9% (REO)
  • 11251

    Neodymium(III) chloride hydrate, REacton®, 99.9% (REO)
  • 11291

    Gadolinium(III) oxide, REacton®, 99.9% (REO)
  • 11300

    Europium(III) oxide, REacton®, 99.9% (REO)
  • 11316

    Dysprosium(III) chloride hydrate, 99.9% (REO)

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