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10026-11-6 - Zirconium(IV) chloride, Reactor Grade, 99.5+% (metals basis) - Zirconium tetrachloride - 12104 - Alfa Aesar

12104 Zirconium(IV) chloride, Reactor Grade, 99.5+% (metals basis)

Numéro CAS
10026-11-6
Synonymes
Zirconium tetrachloride

Dimensions Prix ($) Quantité Disponibilité
10g 25,15
100g 35,68
500g 119,42
2kg 336,81
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Zirconium(IV) chloride, Reactor Grade, 99.5+% (metals basis)

MDL
MFCD00011306
EINECS
233-058-2

Propriétés chimiques

Formule
ZrCl4
Poids formulaire
233.03
Forme
Powder
Point de fusion
331° subl.
Densité
2.803
Sensibilité
Moisture Sensitive
Solubilité
Soluble in alcohol, ether, hydrochloric acid.

Applications

Zirconium tetrachloride is commonly utilized as a Lewis acid catalyst in many organic synthesis reactions. It is an important source for organometallic complexes of zirconium. It is practiced in many areas like nuclear industry, metal industry, photography, glass, and ceramic industry.

Notes

It is stable under room temperatures. Strongly hygroscopic and decomposes in water forming ZrOCl<sub>2</sub> and HCl.

Références bibliographiques

Meshram, H. M.; Premalatha, K.; Rameshbabu, K.; Eeshwaraiah, B.; Yadav, J. S. Zirconium(IV) Chloride Catalyzed Cyclization of ortho-Allylphenols: Synthesis of 2-Methyl-2,3-dihydrobenzofurans. Synth. Commun. 2004, 34 (17), 3091-3097.

Smitha, G.; Chandrasekhar, S.; Sanjeeva Reddy, C. Applications of Zirconium(IV) Chloride in Organic Synthesis. Synthesis 2008, 6, 829-855.

Mentions de danger et de prudence du SGH

Mentions de danger (UE): H314-H318-H302

Causes severe skin burns and eye damage. Causes serious eye damage. Harmful if swallowed.

Mentions de prudence: P260-P280-P303+P361+P353-P305+P351+P338-P301+P330+P331-P304+P340-P310-P301+P312-P405-P501a

Do not breathe dust/fume/gas/mist/vapours/spray. Wear protective gloves/protective clothing/eye protection/face protection. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Immediately call a POISON CENTER or doctor/physician. Call a POISON CENTER or doctor/physician if you feel unwell. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

Autres références

Merck
14,10174
Classe de danger
8
Groupe d'emballage
III
Code tarifaire harmonisé
2827.39
TSCA
Yes
RTECS
ZH7175000

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