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7782-61-8 - Iron(III) nitrate nonahydrate, 98+% (metals basis) - 12226 - Alfa Aesar

12226 Iron(III) nitrate nonahydrate, 98+% (metals basis)

Numéro de CAS
7782-61-8
Synonymes

Conditionnement Prix ($) Quantité Disponibilité
100g 21,30
1kg 44,10
5kg 83,50
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Iron(III) nitrate nonahydrate, 98+% (metals basis)

MDL
MFCD00149708
EINECS
233-899-5

Propriétés chimiques

Formule
FeN3O9•9H2O
Poids moleculaire
403.99 (241.86anhy)
Forme
Crystalline, Contains excess HNO3
Point de fusion
47°
Point d'ébullition
125° dec.
Densité
1.684
Sensibilité
Moisture Sensitive
Solubilité
Soluble in water, alcohol and acetone.

Applications

It is used as catalyst for the synthesis of sodium amide from sodium and ammonia, and for etching of silver and silver alloys. Ferric nitrate is used in the synthesis of organically templated iron phosphates, and acts as an efficient catalyst in enamination of beta dicarbonyl compounds to beta enaminones. Ferric nitrate impregnated clays are useful as oxidizing agents. Clayfen, produced from ferric nitrate and montmorillonite, is used for the oxidation of thiols to disulfide, and alcohols to aldehydes. Ferric nitrate is useful for regio- and stereo-selective nitration of various aromatic, aliphatic, and heteroaromatic olefins. This reaction provides nitroolefins with excellent E-selectivity. With Keggin-type heteropoly acids, it selectively oxidizes various hydroxy groups.

Notes

Keep away from materials like organic and powdered metals.

Références bibliographiques

Soni, P. A.; Gupta, P. K.; Maurya, C. K.; Halve, A. K.; Ganesan, K. Synthesis of 1,2-diones from 1,2-diols using iron(III) nitrate as oxidant under microwave irradiation. Tetrahedron Lett. 2015, 56 (21), 2817-2819.

Jastrzebski, R.; Van den Berg, E. J.; Weckhuysen, B. M.; Bruijnincx, P. C. A. Sustainable production of dimethyl adipate by non-heme iron(III) catalysed oxidative cleavage of catechol. Catal. Sci. Technol. 2015, 5, 2103-2109.

Mentions de danger et de prudence du SGH

Mentions de danger (UE): H272-H315-H319

May intensify fire; oxidizer. Causes skin irritation. Causes serious eye irritation.

Mentions de prudence: P221-P210v-P220-P280a-P305+P351+P338-P501a

Take any precaution to avoid mixing with combustibles. Keep/Store away from clothing/combustible materials. Wear protective gloves and eye/face protection. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Dispose of contents/container in accordance with local/regional/national/international regulations.

Autres références

Merck
14,4027
Classe de danger
5.1
Groupe d'emballage
III
Code tarifaire harmonisé
2834.29
TSCA
Yes
RTECS
NO7175000

Recommandé

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    Nickel(II) nitrate hexahydrate, 98%
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    Manganese(II) nitrate tetrahydrate, 98%
  • 11341

    Cobalt(II) nitrate hexahydrate, 97.7% min
  • 11565

    Chromium(III) nitrate nonahydrate, 98.5%
  • 12357

    Iron(III) chloride, anhydrous, 98%

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