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10035-06-0 - Bismuth(III) nitrate pentahydrate, ACS, 98% - 12231 - Alfa Aesar

12231 Bismuth(III) nitrate pentahydrate, ACS, 98%

Numéro CAS
10035-06-0
Synonymes

Dimensions Prix ($) Quantité Disponibilité
250g 42,91
1kg 128,75
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Bismuth(III) nitrate pentahydrate, ACS, 98%

MDL
MFCD00149157
EINECS
233-791-8

Propriétés chimiques

Formule
Bi(NO3)3•5H2O
Poids formulaire
485.07 (394.99anhy)
Forme
Crystalline
Point de fusion
30° dec.
Densité
2.83
Sensibilité
Hygroscopic
Solubilité
Soluble in dilute HNO{3} acid solution. Decomposes in water to subnitrate. Soluble in dilute acetic acid, glycerol, acetone. Insoluble in alcohol, ethyl acetateSoluble in acetone, acetic acid and glycerol. Insoluble in ethanol and ethyl acetate.

Spécifications des grades

Maximum level of impurities: Insoluble matter 0.005%, Cl 0.001%, SO<sub>4</sub> 0.005%, As 0.001%, Cu 0.002%, Fe 0.001%, Pb 0.002%, K 0.01%, Na 0.02%, Ag 0.001%

Applications

Luminous paints, preparation of bismuth saltsBismuth(III) nitrate pentahydrate is an oxidant for a variety of 4-substituted Hantzsch 1,4-dihydropyridines. It also serves as a reagent for selective oxidation of sufides to sulfoxides. Further, it is involved in the preparation of Dragendorff reagent and used as a TLC stain. It is also used to prepare other bismuth compounds.

Notes

Hygroscopic. Moisture sensitive. Incompatible with strong acids, strong reducing agents, strong oxidizing agents, powdered metals and organic materials.

Références bibliographiques

Zahedifar, M.; Sheibani, H. Rapid three-component synthesis of pyrimidine and pyrimidinone derivatives in the presence of Bi(NO3) 3· 5H2O as a mild and highly efficient catalyst. Res. Chem. Intermed. 2015, 41 (1), 105-111.

Pei, C. C.; Leung, W. W. F. Photocatalytic oxidation of nitrogen monoxide and o-xylene by TiO2/ZnO/Bi2O3 nanofibers: Optimization, kinetic modeling and mechanisms. Appl. Catal., B 2015, 174, 515-525.

Mentions de danger et de prudence du SGH

Mentions de danger (UE): H272-H315-H319-H335-H303

May intensify fire; oxidizer. Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation. May be harmful if swallowed.

Mentions de prudence: P221-P210-P220-P261-P280-P305+P351+P338-P304+P340-P362-P405-P501a

Take any precaution to avoid mixing with combustibles. Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Keep/Store away from clothing/combustible materials. Avoid breathing dust/fume/gas/mist/vapours/spray. Wear protective gloves/protective clothing/eye protection/face protection. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Take off contaminated clothing and wash before reuse. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

Autres références

Merck
14,1271
Classe de danger
5.1
Groupe d'emballage
II
Code tarifaire harmonisé
2834.29
TSCA
Yes

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