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12307 Zinc chloride, ACS, 97% min

Numéro de CAS
7646-85-7
Synonymes

Stock No. Conditionnement Prix ($) Quantité Disponibilité
12307-30 250g 52,30
12307-A1 1kg 132,00
12307-A7 5kg 493,00
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Zinc chloride, ACS, 97% min

MDL
MFCD00011295
EINECS
231-592-0

Propriétés chimiques

Formule
Cl2Zn
Poids moleculaire
136.29
Forme
Lump
Point de fusion
290°
Point d'ébullition
732°
Densité
2.91
Storage & Sensitivity
Hygroscopic. Store under Nitrogen. Ambient temperatures.
Solubilité
Freely soluble in water, and dilute HCl. Soluble in alcohol, glycerol, ether and acetone.

Spécifications des grades

Maximum level of impurities: Oxychloride P.T., Insoluble matter 0.005%, Ca 0.06%, Mg 0.01%, NO3 0.003%, SO4 0.01%, NH4 0.005%, Fe 0.001%, Pb 0.005%, K 0.02%, Na 0.05%

Applications

It is used as a catalyst, as a dehydrating and condensing agent, soldering flux, and metal etchant. It is also employed in preserving anatomical specimens, wood preservatives, deodorant, disinfecting and embalming materials. It is likewise employed as a mordant in printing and dyeing materials, and in the vulcanizing processes of fiber and rubber. It is useful as an electrolyte in dry cell batteries, in metal industry, in galvanizing iron and as an electrolyte for electroplating. It is useful in organic synthesis, for example in the Friedel-Crafts acylatoin, Fisher indole synthesis, Lucas reagent (zinc chloride with HCl), activation of allylic/benzylic halides towards reaction with olefins or with sodium cyanoborohydride catalyzed reduction of halides, organozinc reagents for use in Negishi coupling, and aldol condensation reactions.

Notes

It is a hygroscopic and a deliquescent compound, and hence it must be kept in air-tight container, in a cool dry place.

Références bibliographiques

Angin, D. Production and characterization of activated carbon from sour cherry stones by zinc chloride. Fuel 2014, 115, 804-811.

Ding, B. P.; Wu, F.; Chen, S. C.; Wang, Y. Z.; Zeng, J. B. Synthesis and characterization of a polyurethane ionene/zinc chloride complex with antibacterial properties. RSC Adv. 2015, 5, 12423-12433.

Mentions de danger et de prudence du SGH

Mentions de danger (UE): H302-H314-H335

Harmful if swallowed. Causes severe skin burns and eye damage. May cause respiratory irritation.

Mentions de prudence: P260-P264b-P270-P271-P280-P303+P361+P353-P304+P340-P305+P351+P338-P310-P330-P331-P363-P501c

Do not breathe dust/fume/gas/mist/vapours/spray. Wash face, hands and any exposed skin thoroughly after handling Do not eat, drink or smoke when using this product. Use only outdoors or in a well-ventilated area. Wear protective gloves/protective clothing/eye protection/face protection. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER or doctor/physician. Rinse mouth. Do NOT induce vomiting. Wash contaminated clothing before reuse. Dispose of contents/ container to an approved waste disposal plant

Autres références

Merck
14,10132
Classe de danger
8
Groupe d'emballage
III
Code tarifaire harmonisé
2827.39
TSCA
Yes
RTECS
ZH1400000

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