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7705-08-0 - Iron(III) chloride, anhydrous, 98% - Ferric chloride - 12357 - Alfa Aesar

12357 Iron(III) chloride, anhydrous, 98%

Numéro CAS
7705-08-0
Synonymes
Ferric chloride

Dimensions Prix ($) Quantité Disponibilité
10g 23,26
100g 29,09
1kg 34,58
5kg 56,62
25kg 222,48
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Iron(III) chloride, anhydrous, 98%

MDL
MFCD00011005
EINECS
231-729-4

Propriétés chimiques

Formule
Cl3Fe
Poids formulaire
162.21
Forme
Crystalline
Point de fusion
306°
Point d'ébullition
316°
Densité
2.90
Sensibilité
Hygroscopic
Solubilité
Freely soluble in methanol, ethanol, ether, and acetone.

Applications

It is used for sewerage treatment of industrial wastes, chloride hydrometallurgy (Silgarin process for the production of silicon), drinking water production, production of precursor for polyvinyl chloride (PVC), and copper-based metals in printed circuit boards. Iron (III) chloride is used as catalyst for the reaction of ethylene with chlorine, as a leaching agent, and as a drying reagent in certain reactions. It is a mild oxidizing agent and converts copper(I) chloride in to copper(II) chloride. As a moderately strong Lewis acid, it catalyzes chlorination of aromatic compounds and Friedel-Crafts reactions. Along with sodium iodide, it brings about reduction of organic azides to corresponding amines. It is useful in the detection of phenols and phenolic derivatives, gamma-hydroxybutyric acids, and also in Trinder spot test for detecting salicylic acids.

Notes

Very sensitive to moisture and corrosive. Incompatible with strong oxidizing agents and forms explosive mixtures with sodium, and potassium.

Références bibliographiques

Zhou, Y.; Xing, X. H.; Liu, Z.; Cui, L.; Yu, A.; Feng, Q.; Yang, H. Enhanced coagulation of ferric chloride aided by tannic acid for phosphorus removal from wastewater. Chemosphere 2008, 72 (2), 290-298.

Sarhan, A. A. O.; Bolm, C. Iron(III) chloride in oxidative C-C coupling reactions. Chem. Soc. Rev. 2009, 38, 2730-2744.

Mentions de danger et de prudence du SGH

Mentions de danger (UE): H314-H318-H302

Causes severe skin burns and eye damage. Causes serious eye damage. Harmful if swallowed.

Mentions de prudence: P280-P305+P351+P338-P309-P310

Wear protective gloves/protective clothing/eye protection/face protection. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF exposed or if you feel unwell: Immediately call a POISON CENTER or doctor/physician.

Autres références

Merck
14,4019
Classe de danger
8
Groupe d'emballage
III
Code tarifaire harmonisé
2827.39
TSCA
Yes
RTECS
LJ9100000

Recommandé

  • B22031

    Cobalt(II) chloride, anhydrous, 97%
  • 11868

    Manganese(II) chloride, 97%
  • 12226

    Iron(III) nitrate nonahydrate, 98+% (metals basis)
  • 12457

    Copper(II) chloride, anhydrous, 98% min
  • 31141

    Iron(II) chloride, anhydrous, 99.5% (metals basis)

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