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7647-10-1 - Palladium(II) chloride, solution, Pd 9.0-11.0% w/w (cont. Pd) - 12623 - Alfa Aesar

12623 Palladium(II) chloride, solution, Pd 9.0-11.0% w/w (cont. Pd)

Numéro CAS
7647-10-1
Synonymes

Dimensions Prix ($) Quantité Disponibilité
(c)1g 141,00
(c)5g 500,00
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Palladium(II) chloride, solution, Pd 9.0-11.0% w/w (cont. Pd)

MDL
MFCD00003558
EINECS
231-596-2

Propriétés chimiques

Formule
PdCl2
Poids formulaire
177.31
Forme
Liquid
Solubilité
Miscible with water, organic solvents and hydrochloric acid.

Applications

Palladium(II) chloride is used to remove the stain present stainless steel . Its solutions are used to test the corrosion-resistance of stainless steel. It is used in carbon monoxide detectors. It is also used for cosmetic tatooing of leukomas in thecornea and in the preparation of palladium(II) iodide by reacting with potassium iodide. It is involved in the synthesis of semiconducting metal-containing polymers. It is used as a catalyst for carbonylation of organic tellurides and deamination of phenethylamines to phenyl substituted pyrroles with copper(I) as co catalyst. It plays an important role in the hydrodimerization of butadiene to form octa-2,7-dien-1-ol.

Notes

Incompatible with organic solvents, acids, ammonia, zinc, strong oxidizing agents, aluminum, magnesium, nitrates and thiocyanates.

Références bibliographiques

Yamaguchi, T.; Yamaguchi, E.; Tada, N.; Itoh, A. Direct ortho-Hydroxylation of 2-Phenylpyridines using Palladium(II) Chloride and Hydrogen Peroxide. Adv. Synth. Catal. 2015, 357 (9), 2017-2021.

Banti, C. N.; Charalampou, D. C.; Kourkoumelis, N.; Owczarzak, A. M.; Kubicki, M.; Hadjikakou, S. K.; Hadjiliadis, N. Mono-nuclear cis-Pd(II) chloride complex of the thio-nucleotide analogue 5-methyl-thiouracil and its biological activity. Polyhedron 2015, 87, 251-258.

Mentions de danger et de prudence du SGH

Mentions de danger (UE): H314-H318-H290-H400-H410-H302-H317

Causes severe skin burns and eye damage. Causes serious eye damage. May be corrosive to metals. Very toxic to aquatic life. Very toxic to aquatic life with long lasting effects. Harmful if swallowed. May cause an allergic skin reaction.

Mentions de prudence: P260-P261-P273-P280-P303+P361+P353-P305+P351+P338-P301+P330+P331-P304+P340-P405-P501a

Do not breathe dust/fume/gas/mist/vapours/spray. Avoid breathing dust/fume/gas/mist/vapours/spray. Avoid release to the environment. Wear protective gloves/protective clothing/eye protection/face protection. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

Autres références

Classe de danger
8
Groupe d'emballage
II
Code tarifaire harmonisé
2843.90
TSCA
Yes

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