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14034 Molybdenum(III) chloride, 99.5% (metals basis)

Numéro de CAS
13478-18-7
Synonymes

Stock No. Conditionnement Prix ($) Quantité Disponibilité
14034-04 2g 53,50
14034-09 10g 178,00
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Molybdenum(III) chloride, 99.5% (metals basis)

MDL
MFCD00014214
EINECS
236-775-9

Propriétés chimiques

Formule
MoCl3
Poids moleculaire
202.32
Forme
-100 Mesh Powder
Point de fusion
dec.
Storage & Sensitivity
Moisture Sensitive. Air Sensitive. Store under Argon. Ambient temperatures.
Solubilité
Soluble in nitric acid and sulfuric acid. Insoluble in water and dilute hydrochloric acid. Slightly soluble in ethanol and diethyl ether.

Applications

Molybdenum(III) chloride reacts with tetrahydrothiophene to form complexes, which catalyze the polymerization and cyclotrimerization of alkynes.

Notes

Hygroscopic. Air and moisture sensitive. Keep the container tightly closed in a dry and well-ventilated place. Incompatible with strong oxidizing agents.

Références bibliographiques

Karpov, V. V.; Volkovich, V. A.; Polovov, I. B.; Rebrin, O. I. Solubility of Transition Metal Halides in Chloroaluminate Melts. ECS Trans. 2014, 64 (4), 211-216.

Nishibayashi, Y. Molybdenum-catalyzed reduction of molecular dinitrogen into ammonia under ambient reaction conditions. C.R. Chim. 2015, 18 (7), 776-784.

Mentions de danger et de prudence du SGH

Mentions de danger (UE): H314-H335

Causes severe skin burns and eye damage. May cause respiratory irritation.

Mentions de prudence: P260-P264b-P271-P280-P301+P330+P331-P303+P361+P353-P304+P340-P305+P351+P338-P310-P363-P501c

Do not breathe dust/fume/gas/mist/vapours/spray. Wash face, hands and any exposed skin thoroughly after handling Use only outdoors or in a well-ventilated area. Wear protective gloves/protective clothing/eye protection/face protection. IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER or doctor/physician. Wash contaminated clothing before reuse. Dispose of contents/ container to an approved waste disposal plant

Autres références

Classe de danger
8
Groupe d'emballage
III
Code tarifaire harmonisé
2827.39
TSCA
Yes
RTECS
QA4681400

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