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14532 Lithium tetrafluoroborate, ultra dry, 99.997% (metals basis)

Numéro de CAS
14283-07-9
Synonymes

Stock No. Conditionnement Prix ($) Quantité Disponibilité
14532-06 5g 218,00
14532-14 25g 908,00
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Lithium tetrafluoroborate, ultra dry, 99.997% (metals basis)

MDL
MFCD00011087
EINECS
238-178-9

Propriétés chimiques

Formule
BF4Li
Poids moleculaire
93.75
Forme
Powder, Ampouled under argon
Point de fusion
293-300° dec.
Storage & Sensitivity
Very Hygroscopic. Store under Argon. Ambient temperatures.
Solubilité
Soluble in water.

Applications

Lithium tetrafluoroborate is a mild Lewis acid for Diels-Alder reactions. Catalyst for mild and efficient aminolysis of oxiranes. It is a reagent used in the preparation of rechargeable lithium-ion batteries.

Notes

Hygroscopic. Store away from oxidizing agents, strong base, acids, water/ moisture.

Références bibliographiques

J S Yadav; B V Reddy, L Chandraiah; K S Reddy. LiBF4-mediated C-glycosylation of glycals with allyltrimethylsilane: a facile synthesis of allyl C-glycosylic compounds. Carbohydrate Research. 2001, 332 (2), 221-224.

Takahiro Ichikawa; Masafumi Yoshio; Atsushi Hamasaki; Junko Kagimoto; Hiroyuki Ohno; Takashi Kato. 3D interconnected ionic nano-channels formed in polymer films: self-organization and polymerization of thermotropic bicontinuous cubic liquid crystals. Journal of the American Chemical Society. 2011, 133 (7), 2163-2169.

Mentions de danger et de prudence du SGH

Mentions de danger (UE): H302-H312-H314-H318-H332

Harmful if swallowed. Harmful in contact with skin. Causes severe skin burns and eye damage. Causes serious eye damage. Harmful if inhaled.

Mentions de prudence: P261-P264b-P270-P271-P280-P301+P312-P303+P361+P353-P304+P340-P305+P351+P338-P310-P312-P330-P362-P501c

Avoid breathing dust/fume/gas/mist/vapours/spray. Wash face, hands and any exposed skin thoroughly after handling Do not eat, drink or smoke when using this product. Use only outdoors or in a well-ventilated area. Wear protective gloves/protective clothing/eye protection/face protection. IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER or doctor/physician. Rinse mouth. Take off contaminated clothing and wash before reuse. Dispose of contents/ container to an approved waste disposal plant

Autres références

Merck
14,5543
Classe de danger
8
Groupe d'emballage
II
Code tarifaire harmonisé
2826.90
TSCA
Yes

Recommandé

  • 11528

    Lithium tetrafluoroborate, 98%
  • 11530

    Lithium hexafluoroarsenate(V), 99%

Consulté récemment

Produits chimiques

Sciences de la vie

Métaux et matériaux

Catalyseurs

Analytique et matériel de laboratoire