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30834 Tetramethylammonium perchlorate

Numéro de CAS
2537-36-2
Synonymes

Stock No. Conditionnement Prix ($) Quantité Disponibilité
30834-14 25g 97,20
30834-22 100g 283,00
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Tetramethylammonium perchlorate

MDL
MFCD00043207
EINECS
219-805-5

Propriétés chimiques

Formule
(CH3)4NClO4
Poids moleculaire
173.60
Forme
Crystalline
Point de fusion
>300°
Storage & Sensitivity
Ambient temperatures.
Solubilité
Soluble in water.

Applications

Tetramethylammonium perchlorate acts as an intermediate in organic and chemical synthesis. It is used as a mobile phase in high performance liquid chromatographic analysis and in the quantitation of olanzapine clozapine and N-desmethylclozapine. It acts as a supporting electrolyte in the electrochemical reduction of electrochemical reduction of 1-bromodecanr, 1-iododecane,2-iodooctane and 2-bromooctane at mercury cathodes.

Notes

Store in a cool and dry place. Keep the container tightly sealed. Protect from heat. Incompatible with strong oxidizing agents, flammable substances, aluminum, sulfur compounds and reducing agents.

Références bibliographiques

Strawsine, L. M.; Sengupta, A.; Raghavachari, K.; Peters, D. G. Direct Reduction of Alkyl Monohalides at Silver in Dimethylformamide: Effects of Position and Identity of the Halogen. ChemElectroChem 2015, 2 (5), 726-736.

Parravicini, G. B.; Marabelli, F.; Floris, F.; Pasquali, V.; Parravicini, J.; Ferloni, P. Thermal evolution of tetramethylammonium tetrafluoborate and perchlorate investigated through dielectric and IR spectroscopy. Mater. Chem. Phys. 2014, 147 (1-2), 120-126.

Mentions de danger et de prudence du SGH

Mentions de danger (UE): H272-H315-H319-H335

May intensify fire; oxidizer. Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.

Mentions de prudence: P210-P220-P221-P261-P264b-P271-P280-P302+P352-P304+P340-P305+P351+P338-P312-P332+P313-P337+P313-P362-P370+P378q-P501c

Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Keep/Store away from clothing/combustible materials. Take any precaution to avoid mixing with combustibles. Avoid breathing dust/fume/gas/mist/vapours/spray. Wash face, hands and any exposed skin thoroughly after handling Use only outdoors or in a well-ventilated area. Wear protective gloves/protective clothing/eye protection/face protection. IF ON SKIN: Wash with plenty of soap and water. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Call a POISON CENTER or doctor/physician if you feel unwell. If skin irritation occurs: Get medical advice/attention. If eye irritation persists: Take off contaminated clothing and wash before reuse. In case of fire: Use CO2, dry chemical, or foam Dispose of contents/ container to an approved waste disposal plant

Autres références

Classe de danger
5.1
Groupe d'emballage
II
Code tarifaire harmonisé
2923.90
TSCA
Yes

Recommandé

Consulté récemment

Produits chimiques

Sciences de la vie

Métaux et matériaux

Catalyseurs

Analytique et matériel de laboratoire