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Sodium perborate tetrahydrate is considered as a source of active hydrogen used in detergents, cleaning products, laundry detergents and bleaches. It finds application as a tooth bleaching agent utilized for tooth. It has antiseptic properties and acts as disinfectant as well as preservative in eye drops. Further, it is mixed with suitable activator, tetraacetylethylenediamine in order to release oxygen at lower temperatures.
Useful, inexpensive oxidant. Reviews: Chemtech, 566 (1991); Tetrahedron, 51, 6145 (1995); Synthesis, 1325 (1995); J. Chem. Soc., Perkin 1, 471 (2000). Examples: Oxidation of secondary alcohols to ketones, and ɑ-hydroxy acids to keto acids: Synthesis, 765 (1989). Mild epoxidation of ɑß-unsaturated ketones: Synth. Commun., 19, 3579 (1989); Tetrahedron Lett., 36, 663 (1995). Partial hydrolysis of nitriles to amides: Tetrahedron, 45, 3299 (1989); Synth. Commun., 20, 563 (1990). Oxidation (in AcOH) of sulfides to sulfoxides or sulfones, arylamines to nitro compounds, and Baeyer-Villiger oxidation of ketones to esters: Tetrahedron, 43, 1753 (1987). Oxidation (in AcOH) of aromatic aldehydes to acids: Tetrahedron, 45, 3299 (1989); or oximes to nitro compounds: Synlett, 337 (1992). Oxidative conversion of organoboranes to alcohols: Org. Synth. Coll., 9, 522 (1998).
In combination with triflic acid for hydroxylation of aromatics: Synlett, 39 (1991).
In combination with acetic anhydride, cyclic acetals are cleaved to their respective esters: Synlett., 329 (1995).
For phase-transfer oxidation of alcohols to ketones, catalyzed by Chromium(VI) oxide, 12522, see: Synth. Commun., 21, 575 (1991).
For a brief feature on uses in synthesis, see: Synlett, 2513 (2006).
Qin, S.; Yin, B.; Zhang, Y.; Zhang, Y. Leaching kinetics of szaibelyite ore in NaOH solution. Hydrometallurgy 2015, 157, 333-339.
Hematian, S.; Hormozi, F. Drying kinetics of coated sodium percarbonate particles in a conical fluidized bed dryer. Powder Technol. 2015, 269, 30-37.
Mentions de danger (UE): H318-H332-H335-H360Df
Causes serious eye damage. Harmful if inhaled. May cause respiratory irritation. May damage the unborn child. Suspected of damaging fertility.
Mentions de prudence: P201-P202-P261-P271-P281-P304+P340-P305+P351+P338-P308+P313-P310-P501c
Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Avoid breathing dust/fume/gas/mist/vapours/spray. Use only outdoors or in a well-ventilated area. Use personal protective equipment as required. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF exposed or concerned: Get medical advice/attention. Immediately call a POISON CENTER or doctor/physician. Dispose of contents/ container to an approved waste disposal plant