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130-95-0 - Quinine, anhydrous, 99% (total base), may cont. up to 5% dihydroquinine - A10459 - Alfa Aesar

A10459 Quinine, anhydrous, 99% (total base), may cont. up to 5% dihydroquinine

Numéro de CAS
130-95-0
Synonymes

Conditionnement Prix ($) Quantité Disponibilité
10g 51,40
50g 170,00
250g 670,00
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Quinine, anhydrous, 99% (total base), may cont. up to 5% dihydroquinine

MDL
MFCD00198096
EINECS
205-003-2

Propriétés chimiques

Formule
C20H24N2O2
Poids moleculaire
324.42
Point de fusion
ca 177° dec.
Sensibilité
Light Sensitive
Solubilité
Soluble in alcohol, chloroform and diethyl ether. Slightly soluble in water and glycerol.

Applications

Quinine is used in photochemistry as a common fluorescence standard and as a resolving agent for chiral acids. It is also useful for treating falciparum malaria, lupus, arthritis and vivax malaria. It acts as a flavor component in tonic water and bitter lemon. It is utilized as the chiral moiety for the ligands used in sharpless asymmetric dihydroxylation. Furthermore, it catalyzes the kinetic resolution of furanones.

Notes

Incompatible with strong oxidizing agents.

Références bibliographiques

Porta, R.; Benaglia, M.; Coccia, F.; Rossi, S.; Puglisi, A. Enantioselective Organocatalysis in Microreactors: Continuous Flow Synthesis of a (S)-Pregabalin Precursor and (S)-Warfarin. Symmetry 2015, 7 (3), 1395-1409.

Porta, R.; Coccia, F.; Annunziata, R.; Puglisi, A. Comparison of Different Polymer-and Silica-Supported 9-Amino-9-deoxy-epi-quinines as Recyclable Organocatalysts. ChemCatChem 2015, 7 (9), 1490-1499.

Kessler, S.; González, J.; Vlimant, M.; Glauser, G.; Guerin, P. M. Quinine and artesunate inhibit feeding in the African malaria mosquito Anopheles gambiae: the role of gustatory organs within the mouthparts. Physiol. Entomol. 2014, 39 (2), 172-182.

Mentions de danger et de prudence du SGH

Mentions de danger (UE): H315-H319-H334-H317-H335

Causes skin irritation. Causes serious eye irritation. May cause allergy or asthma symptoms or breathing difficulties if inhaled. May cause an allergic skin reaction. May cause respiratory irritation.

Mentions de prudence: P284-P261-P280a-P305+P351+P338-P405-P501a

Wear respiratory protection. Avoid breathing dust/fume/gas/mist/vapours/spray. Wear protective gloves and eye/face protection. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

Autres références

Merck
14,8061
Beilstein
91867
Code tarifaire harmonisé
2939.20
TSCA
No
RTECS
VA6020000

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Analytique et matériel de laboratoire