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370-81-0 - Bis(cyclohexanone) oxaldihydrazone, 98% - Oxalic acid bis(cyclohexylidenehydrazide) - Cuprizon I - A10628 - Alfa Aesar

A10628 Bis(cyclohexanone) oxaldihydrazone, 98%

Numéro CAS
370-81-0
Synonymes
Oxalic acid bis(cyclohexylidenehydrazide)
Cuprizon I

Dimensions Prix ($) Quantité Disponibilité
25g 39,80
100g 128,00
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Bis(cyclohexanone) oxaldihydrazone, 98%

MDL
MFCD00001659
EINECS
206-729-2

Propriétés chimiques

Formule
C14H22N4O2
Poids formulaire
278.36
Point de fusion
208-212°
Solubilité
Soluble in alcohol. Insoluble in water.

Applications

Bis(cyclohexanone) oxaldihydrazone is used in the quantitative spectroscopic determination of copper. It is also essential for the experimental study of mitochondrial metabolism. It is used to study the human demyelinating diseases such as multiple sclerosis and components of neuroinflammation. Further, it acts as ligand and catalyzes Ullmann-type C-N bond forming reactions in the presence of copper salt.

Notes

Incompatible with strong oxidizing agents and strong bases.

Références bibliographiques

Reagent for spectrophotometric determination of Cu(II): Anal. Chem., 38, 911 (1966).

Krauspe, B. M.; Dreher, W.; Beyer, C.; Baumgartner, W.; Denecke, B.; Janssen, K.; Langhans, C. D.; Clarner, T.; Kipp, M. Short-Term Cuprizone Feeding VerifiesN-Acetylaspartate Quantification as a Marker of Neurodegeneration. J. Mol. Neurosci. 2015, 55 (3), 733-748.

Slowik, A.; Schmidt, T.; Beyer, C.; Amor, S.; Clarner, T.; Kipp, M. The sphingosine 1-phosphate receptor agonist FTY720 is neuroprotective after cuprizone-induced CNS demyelination. Br. J. Pharmacol. 2015, 172 (1), 80-92.

Mentions de danger et de prudence du SGH

Mentions de danger (UE): H315-H319-H335

Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.

Mentions de prudence: P261-P280-P305+P351+P338-P304+P340-P362-P312-P321-P405-P403+P233-P501a

Avoid breathing dust/fume/gas/mist/vapours/spray. Wear protective gloves/protective clothing/eye protection/face protection. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Take off contaminated clothing and wash before reuse. Call a POISON CENTER or doctor/physician if you feel unwell. Specific treatment (see label). Store locked up. Store in a well-ventilated place. Keep container tightly closed. Dispose of contents/container in accordance with local/regional/national/international regulations.

Autres références

Beilstein
2388004
Code tarifaire harmonisé
2928.00
TSCA
Yes
RTECS
RO2520000

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Catalyseurs

Analytique et matériel de laboratoire