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29558-77-8 - 4-Bromo-4'-hydroxybiphenyl, 98% - A10819 - Alfa Aesar

A10819 4-Bromo-4'-hydroxybiphenyl, 98%

Numéro CAS
29558-77-8
Synonymes

Dimensions Prix ($) Quantité Disponibilité
5g 38,52
25g 128,80
100g 364,30
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4-Bromo-4'-hydroxybiphenyl, 98%

MDL
MFCD00059076

Propriétés chimiques

Formule
C12H9BrO
Poids formulaire
249.11
Point de fusion
163-168°
Solubilité
Soluble in water (partly), and methanol.

Applications

A biphenyl starting material. 4?-Bromo-(1,1?-biphenyl)-4-ol is a useful intermediate. Vinylation of 4-bromo-4?-hydroxybiphenyl and ethyl acrylate using Pd (OAc) 2/PPh 3 catalyst was studied. Ethyl 4-(4?-hydroxyphenyl) cinnamate was formed as the vinylation product, while, 4-hydroxybiphenyl and ethyl cinnamate were formed as side products. Preparation of 4-cyano-4'-hydroxybiphenyl This was prepared from 4-bromo-4'-benzenesulphonyloxybiphenyl by first hydrolysing it to 4-bromo-4-hydroxybiphenyl using sodium hydroxide dissolved in a mixture of water and dioxan. The syntheses of the Nanocomposite dendrimers based on cyclic phosphazene cores: Amorphous materials, were accomplished by following a modified literature procedure by reacting phosphonitrilic chloride trimer with 4-bromophenol or 4-bromo-4?-hydroxybiphenyl, respectively, in the presence of K 2 CO 3 in tetrahydrofuran (THF).

Notes

Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Store away from strong oxidizing agents.

Références bibliographiques

Ashutosh Anant Kelkara,; Taka-aki Hanaoka,; Yoshihiro Kubota,; Yoshihiro Sugi. Palladium catalyzed vinylation of 4-bromo-4?-hydroxybiphenyl. Journal of Molecular Catalysis. 1994, 88 (2) ,L113-L116.

Sierra Rayne,; Michael G Ikonomou,; MacMurray D Whale. Anaerobic microbial and photochemical degradation of 4,4?-dibromodiphenyl ether. Water Research. 2003, 37(3), 551-560.

Mentions de danger et de prudence du SGH

Mentions de danger (UE): H315-H319-H335

Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.

Mentions de prudence: P261-P280-P305+P351+P338-P304+P340-P362-P312-P321-P405-P403+P233-P501a

Avoid breathing dust/fume/gas/mist/vapours/spray. Wear protective gloves/protective clothing/eye protection/face protection. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Take off contaminated clothing and wash before reuse. Call a POISON CENTER or doctor/physician if you feel unwell. Specific treatment (see label). Store locked up. Store in a well-ventilated place. Keep container tightly closed. Dispose of contents/container in accordance with local/regional/national/international regulations.

Autres références

Code tarifaire harmonisé
2908.19
TSCA
No

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Analytique et matériel de laboratoire