Consentement d'utilisation des Cookies

J'accepte Notre site sauvegarde des traceurs textes (cookies) sur votre appareil afin de vous garantir de meilleurs contenus et à des fins de collectes statistiques.Vous pouvez désactiver l'usage des cookies en changeant les paramètres de votre navigateur. En poursuivant votre navigation sur notre site sans changer vos paramètres de navigateur vous nous accordez la permission de conserver des informations sur votre appareil.

1663-45-2 - 1,2-Bis(diphenylphosphino)ethane, 97+% - Diphos - Dppe - A11419 - Alfa Aesar

A11419 1,2-Bis(diphenylphosphino)ethane, 97+%

Numéro CAS
1663-45-2
Synonymes
Diphos
Dppe

Dimensions Prix ($) Quantité Disponibilité
5g 36,40
25g 105,00
100g 382,00
Ajouter au panier Ajouter au devis en vrac Afficher l'article

1,2-Bis(diphenylphosphino)ethane, 97+%

MDL
MFCD00003047
EINECS
216-769-2

Propriétés chimiques

Formule
C26H24P2
Poids formulaire
398.42
Point de fusion
138-143°
Sensibilité
Air Sensitive
Solubilité
Soluble in acetone, methanol and alcoholic hydrochloric acid.

Applications

1,2-Bis(diphenylphosphino)ethane is a bidendate ligand used in coordination chemistry to prepare metal complexes. It is involved in the metal-catalyzed allylic alkylation and decarboxylation of allylic esters. It is also used in 1,3-diene synthesis. Further, it is used in cycloaddition reactions and carbonylation reactions. In addition to this, it is used to prepare bis(dicyclohexylphosphino)ethane by hydrogenation.

Notes

Air sensitive. Incompatible with strong oxidizing agents.

Références bibliographiques

Chelating phosphorus ligand.

The complex with NiCl2 catalyzes the coupling of haloaromatic compounds with Grignard reagents: J. Org. Chem., 49, 478 (1984).

The catalyst prepared in situ with Sodium tetrachloropalladate(II)­ hydrate, 11886, catalyzes the carbonylation of allylic halides at atmospheric pressure: Chem. Lett., 1873 (1989):

Useful replacement for Triphenyl­phosphine, L02502, in the Staudinger and Mitsunobu reactions, with the advantage of easier separation of the by-product bis(phosphine oxide) due to its higher polarity compared with triphenylphosphine oxide: Tetrahedron Lett., 39, 7787 (1998). Has also been used as an alternative to PPh3 for the halodehydroxylation of alcohols, e.g. in combination with Hexachloroethane, L14297, alkyl chlorides are formed; the phosphine oxide by-product can readily be separated by filtration: Tetrahedron Lett., 42, 2459 (2001).

Afonin, M. Y.; Smolentsev, A. I.; Konchenko, S. N.; Petrov, P. A. Cyanato- and thiocyanato-substituted triangular clusters of molybdenum, [Mo3S4(dppe)3X3]+ (X = NCO-, NCS-; dppe = 1,2-bis(diphenylphosphino)ethane). J. Coord. Chem. 2015, 68 (3), 422-431.

Bloomfield, A. J.; Sheehan, S. W.; Collom, S. L.; Crabtree, R. H.; Anastas, P. T. A heterogeneous water oxidation catalyst from dicobalt octacarbonyl and 1,2-bis(diphenylphosphino)ethane. New J. Chem. 2014, 38 (4), 1540-1545.

Mentions de danger et de prudence du SGH

Mentions de danger (UE): H315-H319-H335

Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.

Mentions de prudence: P280g-P305+P351+P338

Wear protective gloves. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.

Autres références

Beilstein
761261
Code tarifaire harmonisé
2931.90
TSCA
Yes

Recommandé

  • A10284

    Dichlorophenylphosphine, 97%
  • A12728

    Silicone oil, for oil baths, usable range from -40 to +200°C
  • A12931

    1,3-Bis(diphenylphosphino)propane, 97%
  • B21112

    Bis(diphenylphosphino)methane, 97%
  • 14112

    Triphenylphosphine, 99+%

Consulté récemment

Produits chimiques

Sciences de la vie

Métaux et matériaux

Catalyseurs

Analytique et matériel de laboratoire