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106-95-6 - Allyl bromide, 99%, stab. with 300-1000ppm Propylene oxide - 3-Bromo-1-propene - A11766 - Alfa Aesar

A11766 Allyl bromide, 99%, stab. with 300-1000ppm Propylene oxide

Numéro de CAS
106-95-6
Synonymes
3-Bromo-1-propene

Conditionnement Prix ($) Quantité Disponibilité
250g 25,20
1000g 68,30
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Allyl bromide, 99%, stab. with 300-1000ppm Propylene oxide

MDL
MFCD00000244
EINECS
203-446-6

Propriétés chimiques

Formule
C3H5Br
Poids moleculaire
120.98
Point de fusion
-119°
Point d'ébullition
70-71°
Point d'éclair
-2°(28°F)
Densité
1.398
Indice de réfraction
1.4700
Sensibilité
Light Sensitive
Solubilité
Slightly miscible with water.

Applications

Allyl bromide is used as an alkylating agent in the synthesis of pharmaceuticals, polymers, adhesives, perfumes, biochemicals and other allylic compounds. It is used as precursor for the preparation of allyliczinc bromide by reacting it with zinc. It is also used in the preparation of allylethers like allyl decyl ether, allyl benzyl ether and allyl geranyl ether. It is also used in the preparation of R enantiomer of allyl phenyl carbinol (APC) such as 1-phenyl-3-butene, which is a valuable intermediate for drugs and agro-chemicals.

Notes

Moisture and light sensitive. Incompatible with oxidizing agents, alkali metals, alkaline earth metals, amides, amines and powdered metals.

Références bibliographiques

Pandey, G.; Kant, R.; Batra, S. A general route to the synthesis of indoloazocines using allyl bromides prepared from Morita-Baylis-Hillman adducts. Tetrahedron Lett. 2015, 56 (7), 930-933.

Fananas-Mastral, M.; Vitale, R.; Perez, M.; Feringa, B. L. Enantioselective Synthesis of All-Carbon Quaternary Stereogenic Centers via Copper-Catalyzed Asymmetric Allylic Alkylation of (Z)-Allyl Bromides with Organolithium Reagents. Chem. Eur. J. 2015, 21 (11), 4209-4212.

Mentions de danger et de prudence du SGH

Mentions de danger (UE): H225-H301-H331-H314-H318-H340-H350

Highly flammable liquid and vapour. Toxic if swallowed. Toxic if inhaled. Causes severe skin burns and eye damage. Causes serious eye damage. May cause genetic defects. May cause cancer.

Mentions de prudence: P210-P301+P310a-P303+P361+P353-P305+P351+P338-P405-P501a

Keep away from heat/sparks/open flames/hot surfaces. - No smoking. IF SWALLOWED: IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

Autres références

Merck
14,288
Classe de danger
3
Groupe d'emballage
I
Code tarifaire harmonisé
2903.39
TSCA
Yes
RTECS
UC7090000

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Analytique et matériel de laboratoire