Consentement d'utilisation des Cookies

J'accepte Notre site sauvegarde des traceurs textes (cookies) sur votre appareil afin de vous garantir de meilleurs contenus et à des fins de collectes statistiques.Vous pouvez désactiver l'usage des cookies en changeant les paramètres de votre navigateur. En poursuivant votre navigation sur notre site sans changer vos paramètres de navigateur vous nous accordez la permission de conserver des informations sur votre appareil.

1600-27-7 - Mercury(II) acetate, 98+% - Acetic acid mercury(II) salt - Mercuric acetate - A12478 - Alfa Aesar

A12478 Mercury(II) acetate, 98+%

Numéro CAS
1600-27-7
Synonymes
Acetic acid mercury(II) salt
Mercuric acetate

Dimensions Prix ($) Quantité Disponibilité
25g 23,60
100g 55,60
500g 168,00
Ajouter au panier Ajouter au devis en vrac Afficher l'article

Mercury(II) acetate, 98+%

MDL
MFCD00012165
EINECS
216-491-1

Propriétés chimiques

Formule
C4H6HgO4
Poids formulaire
318.68
Point de fusion
179-182°
Densité
3.28
Sensibilité
Light Sensitive
Solubilité
Soluble in water.

Applications

Mercury(II) acetate is used as a reagent to prepare organomercury compounds and to remove the acetamidomethyl protecting group in organic synthesis. It is also involved in the oxymercuration reactions as well as to prepare dithiocarbonates from thiocarboantes.It finds application as a catalyst in organic synthesis, pharmaceuticals and absorption of ethylene.

Notes

Light sensitive. Incompatible with strong oxidizing agents, strong acids and strong bases.

Références bibliographiques

The solvomercuration of alkenes by Hg(OAc)2, with demercuration by NaBH4, is a useful method for the Markovnikov hydration of alkenes; reviews: Angew. Chem. Int. Ed., 17, 27 (1978); Tetrahedron, 38, 1713 (1982). See, e.g.: Org. Synth. Coll., 6, 766 (1988):

Intramolecular oxy- or amino-mercuration is a useful route to oxygen or nitrogen heterocycles: J. Heterocycl. Chem., 11, 771 (1974); 13, 349 (1976); 15, 1313 (1978):

For an improved method for the synthesis of substituted pyrrolidines using TBTH as reducing agent, avoiding the reaction reversal encountered with borohydride, see: Synth. Commun., 26, 1507 (1996).

Mercuration/demercuration of aliphatic isocyanates provides a mild route to primary amines: Tetrahedron Lett., 36, 8859 (1995).

For a review of organomercurials in synthesis, see: Tetrahedron, 38, 1713 (1982).

Schmidt, E. Y.; Vasil’tsov, A. M.; Zorina, N. V.; Ivanov, A. V.; Mikhaleva, A. I.; Trofimov, B. A. Devinylation of N-vinylpyrroles using mercury(II) acetate. Chem. Heterocycl. Compd. 2012, 47 (10), 1300-1303.

Dehghanpour, S.; Jahani, K.; Mahmoudi, A.; Babakhodaverdi, M.; Notash, B. In situ hydrothermal synthesis of 2D mercury(I)-organic framework from 3-aminopyrazine-2-carboxylic acid and mercury(II) acetate. Inorg. Chem. Commun. 2012, 25, 79-82.

Mentions de danger et de prudence du SGH

Mentions de danger (UE): H300-H310-H330-H373-H400-H410

Fatal if swallowed. Fatal in contact with skin. Fatal if inhaled. May cause damage to organs through prolonged or repeated exposure. Very toxic to aquatic life. Very toxic to aquatic life with long lasting effects.

Mentions de prudence: P273-P280h-P309-P310-P302+P352-P501a

Avoid release to the environment. Wear protective gloves/clothing. IF exposed or if you feel unwell: Immediately call a POISON CENTER or doctor/physician. IF ON SKIN: Wash with plenty of soap and water. Dispose of contents/container in accordance with local/regional/national/international regulations.

Autres références

Merck
14,5873
Beilstein
3563831
Classe de danger
6.1
Groupe d'emballage
II
Code tarifaire harmonisé
2852.10
TSCA
Yes
RTECS
AI8575000

Recommandé

Consulté récemment

Produits chimiques

Sciences de la vie

Métaux et matériaux

Catalyseurs

Analytique et matériel de laboratoire