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1072-71-5 - 2,5-Dimercapto-1,3,4-thiadiazole, 97% (dry wt.), water <3% - Bismuthiol I - 1,3,4-Thiadiazole-2,5-dithiol - A12615 - Alfa Aesar

A12615 2,5-Dimercapto-1,3,4-thiadiazole, 97% (dry wt.), water <3%

Numéro de CAS
1072-71-5
Synonymes
Bismuthiol I
1,3,4-Thiadiazole-2,5-dithiol

Conditionnement Prix ($) Quantité Disponibilité
50g 36,30
250g 162,00
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2,5-Dimercapto-1,3,4-thiadiazole, 97% (dry wt.), water <3%

MDL
MFCD00003103
EINECS
214-014-1

Propriétés chimiques

Formule
C2H2N2S3
Poids moleculaire
150.24
Point de fusion
ca 162° dec.
Solubilité
Soluble in water.

Applications

2,5-Dimercapto-1,3,4-thiadiazole is used in synthesizing polymers and heavy metal and basic salts. It acts as an additive in lubricating oils, greases and in electrode compositions. It also acts as an intermediate for pharmaceuticals and dyes, as a chelating agent in the analysis of metals. It also serves as an anticorrosion and antirust agent.

Notes

Incompatible with strong oxidizing agents and strong acids.

Références bibliographiques

Reagent for bismuth.

/n

Pan, Y- C.; Wen, Y.; Xue, L-Y.; Guo, X-Y.; Yang, H-F. Adsorption Behavior of Methimazole Monolayers on a Copper Surface and Its Corrosion Inhibition. J. Phys. Chem. C 2012,116 (5), 3532-3538.

Chen, W.; Luo, H. Q.; Li, B. N. Inhibition effects of 2,5-dimercapto-1,3,4-thiadiazole on the corrosion of mild steel in sulphuric acid solution. Corros. Sci. 2011,53 (10), 3356-3365.

Pan, Y-C.; Wen, Y.; Guo, X-Y.; Song, P.; Shen, S.; Du, Y-P.; Yang, H-F. 2-Amino-5-(4-pyridinyl)-1,3,4-thiadiazole monolayers on copper surface: Observation of the relationship between its corrosion inhibition and adsorption structure. Corros. Sci. 2013, 73,274-280.

Rodríguez-Calero, G. G.; Conte, S.; Lowe, M. A.; Gao, J.; Kiya, Y.; Henderson, J. C.; Abruña, H. D. Synthesis and Characterization of Poly-3,4-ethylenedioxythiophene/2,5-Dimercapto-1,3,4-thiadiazole (PEDOT-DMcT) Hybrids. Electrochim. Acta. 2015, 167, 55-60.

Mentions de danger et de prudence du SGH

Mentions de danger (UE): H315-H319-H335

Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.

Mentions de prudence: P261-P280a-P305+P351+P338-P304+P340-P405-P501a

Avoid breathing dust/fume/gas/mist/vapours/spray. Wear protective gloves and eye/face protection. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

Autres références

Beilstein
113444
Code tarifaire harmonisé
2934.99
TSCA
Yes
RTECS
XI3850000

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