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86-93-1 - 1-Phenyl-1H-tetrazole-5-thiol, 99% - 5-Mercapto-1-phenyl-1H-tetrazole - A12656 - Alfa Aesar

A12656 1-Phenyl-1H-tetrazole-5-thiol, 99%

Numéro CAS
86-93-1
Synonymes
5-Mercapto-1-phenyl-1H-tetrazole

Dimensions Prix ($) Quantité Disponibilité
25g 34,51
100g 131,84
500g 418,40
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1-Phenyl-1H-tetrazole-5-thiol, 99%

MDL
MFCD00003129
EINECS
201-710-5

Propriétés chimiques

Formule
C7H6N4S
Poids formulaire
178.22
Point de fusion
ca 145° dec.
Point d'éclair
138°(280°F)
Sensibilité
Air Sensitive
Solubilité
Soluble in 5% ethanol, water (partly), acetone, chloroform, and methanol.

Applications

1-Phenyl-1H-tetrazole-5-thiol is an effective inhibitor of aluminum corrosion in 1M HCl solution. 1-Phenyl-1H-tetrazole-5-thiol was used in the synthesis of oxacyclic building blocks via highly stereoselective radical cyclization and olefin metathesis reactions. It was also used in the synthesis of metalated tetradecyl sulfone. It is also used in the spectrophotometric determination of Pt and Bi.

Notes

Air Sensitive. Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Stable under recommended storage conditions. Keep away from oxidizing agents.

Références bibliographiques

R Cea-Olivares.; OJ Sandoval.; G Espinosa-Perez. New organotin(IV) derivatives of 1-phenyl-1H-tetrazole-5-thiol. Crystal and molecular structure of 1?[Bz3SnSCN4Ph], a polymer built through secondary intermolecular Sn?N bonds. Polyhedron. 2008, 13, (19), 2809-2818.

C Ma.; J Sun. Hydrogen bonding and π-π stacking interaction in the coordination of sulfur and nitrogen donor heterocycle to organotin(IV): syntheses and crystal structures of di- and triorganotin(IV) derivatives with 1-(4-hydroxyphenyl)-1H-tetrazole-5-thiol. Polyhedron. 2004, 23, (9), 2809-2818.

In combination with t-butyl isocyanide, promotes the lactonization of long-chain hydroxy acids: Angew. Chem. Int. Ed., 20, 771 (1981).

Mentions de danger et de prudence du SGH

Mentions de danger (UE): H228

Flammable solid.

Mentions de prudence: P210-P280-P240-P241-P370+P378a

Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Wear protective gloves/protective clothing/eye protection/face protection. Ground/bond container and receiving equipment. Use explosion-proof electrical/ventilating/lighting/ equipment. In case of fire: Use for extinction: CO2, powder or water spray.

Autres références

Beilstein
139068
Classe de danger
4.1
Groupe d'emballage
III
Code tarifaire harmonisé
2933.99
TSCA
Yes
RTECS
XF7700000

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Analytique et matériel de laboratoire