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107-13-1 - Acrylonitrile, 99+%, stab. with ca 40ppm 4-methoxyphenol - Propenenitrile - Vinyl cyanide - A13058 - Alfa Aesar

A13058 Acrylonitrile, 99+%, stab. with ca 40ppm 4-methoxyphenol

Numéro CAS
Vinyl cyanide

Dimensions Prix ($) Quantité Disponibilité
100ml 15,00
500ml 23,50
2500ml 70,00
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Acrylonitrile, 99+%, stab. with ca 40ppm 4-methoxyphenol


Propriétés chimiques

Poids formulaire
Point de fusion
Point d'ébullition
Point d'éclair
Indice de réfraction
Light Sensitive
Miscible with isopropanol, ethanol, ether, acetone, water, carbon tetrachloride, ethyl acetate, toluene and benzene.


Acrylonitrile acts as a monomer used in the production of polyacrlonitrile plastics, adhesives and synthetic rubber. It is also used for the synthesis of copolymers such as styrene-acrylonitrile, acrylonitrile butadiene styrene, acrylonitrile styrene acrylate. It is involved in the preparation of adiponitrile by dimerization, which finds application in polyamide synthesis. It acts as a precursor to acrylamide and acrylic acid. It is used as dienophile in Diels-Alder reactions. It acts as a chemical intermediate in the synthesis of antioxidants, active pharmaceutical ingredients, dyes, and surface-active agents. Further, it is utilized for the preparation of acrylic fibers, resins and nitrile rubbers. In addition to this, it serves as a fumigant for food commodities, flour milling, and bakery food processing equipment.


Light sensitive. Incompatible with oxidizing agents, acids, alkalis, metals, bromine, peroxides and copper.

Références bibliographiques

The Stetter reaction (conjugate addition of aryl aldehydes) catalyzed by CN-, is exemplified by the addition of pyridine-3-carboxaldehyde to acrylonitrile to give 4-oxo-4-(3-pyridyl)butyronitrile: Org. Synth. Coll., 6, 866 (1988). See also 3-Benzyl-5-(2-hydroxyethyl)-4-methyl­thiazolium chloride, L08750.

Free radical alkylation, acylation and arylation reactions also occur in the presence of t-butyl hydroperoxide and a Cu(II) catalyst: J. Chem. Soc., Chem. Commun., 1399 (1995). Several other free radical procedures have been reported involving intramolecular homolytic aromatic substitution to give carbocyclic and heterocyclic systems: Tetrahedron Lett., 36, 4307 (1995):

The reaction is also applicable to acrylate esters and vinyl ketones; with acrylonitrile and phenoxyacetic acid, tetrahydrobenzopyran-4-carbonitrile is obtained in 41% yield.

Dai, Y.; Song, Y.; Tu, X.; Jiang, Y.; Yuan, Y. Sequential shape-selective adsorption and photocatalytic transformation of acrylonitrile production wastewater. Water Res. 2015, 85, 216-225.

Pan, X.; Lamson, M.; Yan, J.; Matyjaszewski, K. Photoinduced Metal-Free Atom Transfer Radical Polymerization of Acrylonitrile. ACS Macro Lett. 2015, 4 (2), 192-196.

Mentions de danger et de prudence du SGH

Mentions de danger (UE): H225-H301-H311-H331-H315-H318-H317-H350-H335

Highly flammable liquid and vapour. Toxic if swallowed. Toxic in contact with skin. Toxic if inhaled. Causes skin irritation. Causes serious eye damage. May cause an allergic skin reaction. May cause cancer. May cause respiratory irritation.

Mentions de prudence: P210-P201-P261-P280-P301+P310a-P303+P361+P353-P305+P351+P338-P304+P340-P405-P501a

Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Obtain special instructions before use. Avoid breathing dust/fume/gas/mist/vapours/spray. Wear protective gloves/protective clothing/eye protection/face protection. IF SWALLOWED: IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

Autres références

Classe de danger
Groupe d'emballage
Code tarifaire harmonisé


  • A13128

    Methyl acrylate, 99%, stab. with ca 15ppm 4-methoxyphenol
  • A16163

    Formaldehyde, 37% w/w aq. soln., stab. with 7-8% methanol
  • A18481

    Styrene, 99%, stab. with 10-15ppm 4-tert-butylcatechol
  • B24815

    2-Hydroxyethyl acrylate, 97%, stab. with 200-300ppm 4-methoxyphenol
  • L02637

    1-Hexadecene, 94%

Consulté récemment

Produits chimiques

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Métaux et matériaux


Analytique et matériel de laboratoire