Consentement d'utilisation des Cookies

J'accepte Notre site sauvegarde des traceurs textes (cookies) sur votre appareil afin de vous garantir de meilleurs contenus et à des fins de collectes statistiques.Vous pouvez désactiver l'usage des cookies en changeant les paramètres de votre navigateur. En poursuivant votre navigation sur notre site sans changer vos paramètres de navigateur vous nous accordez la permission de conserver des informations sur votre appareil.

4426-47-5 - 1-Butylboronic acid, 98% - n-Butaneboronic acid - A13725 - Alfa Aesar

A13725 1-Butylboronic acid, 98%

Numéro CAS
4426-47-5
Synonymes
n-Butaneboronic acid

Dimensions Prix ($) Quantité Disponibilité
1g 25,90
5g 85,50
25g 317,00
Ajouter au panier Ajouter au devis en vrac Afficher l'article

1-Butylboronic acid, 98%

MDL
MFCD00002106
EINECS
224-607-7

Propriétés chimiques

Formule
CH3CH2CH2CH2B(OH)2
Poids formulaire
101.94
Point de fusion
92-96°
Sensibilité
Air Sensitive & Hygroscopic
Solubilité
Soluble in water.

Applications

1-Butylboronic acid is used as a reagent for preparation of volatile derivatives of diols, e.g. carbohydrates, for GC and mass spectrometry and to prepare chiral oxazaborolidines. It is a precursor to unsymmetric borinic acids, which are inhibitors of serine proteases. Can be used as a transport carrier in membrane-based sugar separations and as an analytical reagent in the determination of serum glucose.

Notes

Keep container tightly sealed. Store in cool, dry conditions in well sealed containers. It is hygroscopic in nature. Incompatible with oxidizing agents. Store under dry inert gas.

Références bibliographiques

Franck Picard.; Tobias Schulz.; Rolf W. Hartmann. 5-Phenyl substituted 1-methyl-2-pyridones and 4?-substituted biphenyl-4-carboxylic acids. synthesis and evaluation as inhibitors of steroid-5α-reductase type 1 and 2. Bioorganic & Medicinal Chemistry. 2002, 10 (2), 437-448.

Zhao Yongliang.; Zhao Fengying.; Li Qiang.; Gao Deqing. Synthesis, Characterization and Fluorescence Properties of Europium, Terbium Complexes with Biphenyl-4-Carboxylic Acid and o-Phenanthroline. Journal of Rare Earths. 2006, 24 (1), 18-22.

Reagent for preparation of volatile derivatives of diols, e.g. carbohydrates, for GC and mass spectrometry: J. Chromat., 54, 193 (1971); J. Chromat. Sci., 9, 18 (1971); Gas Chromat., 129 (1968).

In combination with (S)-(-)-ɑ,ɑ-Diphenyl­prolinol, L09217, or its enantiomer (9218), oxazaborolidine catalysts are generated in situ, for use in highly enantioselective reductions: Tetrahedron Lett., 33, 4141 (1992). The same system has been employed in the synthesis of chiral monosubstituted oxiranes: Tetrahedron Lett., 34, 5227 (1993). See also (S)-2-Methyl-CBS-oxazaborolidine monohydrate, L09219, and Appendix 5.

Mentions de danger et de prudence du SGH

Mentions de danger (UE): H315-H319-H335

Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.

Mentions de prudence: P261-P280-P305+P351+P338-P304+P340-P362-P312-P321-P405-P403+P233-P501a

Avoid breathing dust/fume/gas/mist/vapours/spray. Wear protective gloves/protective clothing/eye protection/face protection. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Take off contaminated clothing and wash before reuse. Call a POISON CENTER or doctor/physician if you feel unwell. Specific treatment (see label). Store locked up. Store in a well-ventilated place. Keep container tightly closed. Dispose of contents/container in accordance with local/regional/national/international regulations.

Autres références

Beilstein
1733489
Code tarifaire harmonisé
2931.90
TSCA
No

Recommandé

  • A18304

    2-Methyl-2-butanol, 98%
  • A18481

    Styrene, 99%, stab. with 10-15ppm 4-tert-butylcatechol
  • B22446

    1-Hexylboronic acid, 97%
  • B23842

    Furan-2-boronic acid, 97%
  • H26893

    3,5-Dimethylisoxazole-4-boronic acid, 97%

Consulté récemment

Produits chimiques

Sciences de la vie

Métaux et matériaux

Catalyseurs

Analytique et matériel de laboratoire