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71-91-0 - Tetraethylammonium bromide, 98% - A13835 - Alfa Aesar

A13835 Tetraethylammonium bromide, 98%

Numéro CAS
71-91-0
Synonymes

Dimensions Prix ($) Quantité Disponibilité
250g 40,41
1000g 117,42
5000g 399,60
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Tetraethylammonium bromide, 98%

MDL
MFCD00011825
EINECS
200-769-4

Propriétés chimiques

Formule
(CH3CH2)4NBr
Poids formulaire
210.16
Point de fusion
ca 285° dec.
Densité
1.397
Sensibilité
Hygroscopic
Solubilité
Soluble in water.

Applications

Tetraethylammonium bromide is used as a phase transfer catalyst. It acts as a source of tetraethylammonium ions in pharmacological and physiological studies. It is also employed in organic chemical synthesis. It plays a major role in the preparation of tetraethylammonium superoxide from potassium superoxide for the conversion of primary alkyl halides to dialkyl peroxides. Furthermore, It is utilized as a catalyst in the oxidation of organic sulfide to sulfoxide using o-iodoxybenzoic acid.

Notes

Hygroscopic. Incompatible with strong oxidizing agents and bases.

Références bibliographiques

Phase-transfer catalyst; see Appendix 2.

For use in combination with anhydrous HBr as a reagent for selective monohydrobromination of an alkyne, see: Org. Synth., 76, 263 (1998).

Takemoto, K.; Yamada, H. Development of rechargeable lithium-bromine batteries with lithium ion conducting solid electrolyte. J. Power Sources 2015, 281, 334-340.

Abdel-Rahman, L. H.; El-Khatib, R. M.; Nassr, L. A.; Abu-Dief, A. M. Salts and Structural Effects on the base Catalyzed Hydrolysis of some Novel and Pharmacologically Active Iron(II) Azomethine Amino Acid Complexes. Int. J. Nano. Chem. 2015, 1 (1), 25-30.

Mentions de danger et de prudence du SGH

Mentions de danger (UE): H315-H319-H335

Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.

Mentions de prudence: P261-P280-P305+P351+P338-P304+P340-P362-P312-P321-P405-P403+P233-P501a

Avoid breathing dust/fume/gas/mist/vapours/spray. Wear protective gloves/protective clothing/eye protection/face protection. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Take off contaminated clothing and wash before reuse. Call a POISON CENTER or doctor/physician if you feel unwell. Specific treatment (see label). Store locked up. Store in a well-ventilated place. Keep container tightly closed. Dispose of contents/container in accordance with local/regional/national/international regulations.

Autres références

Merck
14,9199
Beilstein
3563430
Code tarifaire harmonisé
2923.90
TSCA
Yes
RTECS
BS5950000

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Analytique et matériel de laboratoire