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15933-59-2 - Tetramethyldisilazane, 97% - A14304 - Alfa Aesar

A14304 Tetramethyldisilazane, 97%

Numéro CAS
15933-59-2
Synonymes

Dimensions Prix ($) Quantité Disponibilité
10g 59,12
50g 196,07
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Tetramethyldisilazane, 97%

MDL
MFCD00025626
EINECS
240-072-2

Propriétés chimiques

Formule
C4H15NSi2
Poids formulaire
133.34
Point d'ébullition
99-100°
Point d'éclair
-3°(26°F)
Densité
0.768
Indice de réfraction
1.4055
Sensibilité
Moisture Sensitive
Solubilité
Miscible with common organic solvents.

Applications

Tetramethyldisilazane is used as a gas chromatographic derivatizing reagent. Further, it reacts with phenol to prepare dimethylphenoxysilane. In addition, it is used in electronic, polymer and pharmaceutical industries.

Notes

Moisture sensitive. Incompatible with strong oxidizing agents.

Références bibliographiques

Reagent for the preparation (see Appendix 4) of dimethylsilyl (DMS) derivatives, compare Hexamethyl­disilazane, A15139. With allylic and homoallylic alcohols, the products can undergo Pt- or Rh-catalyzed intramolecular hydrosilylation, providing a regioselective route to 1,3-diols: J. Am. Chem. Soc., 108, 6090 (1986). For an example of this reaction, see Chlorodimethyl­silane, A13113.

The potassium derivative, formed by reaction with KH in THF, reacts with alkyl halides to give, after hydrolysis, high yields of primary amines, thus providing a convenient alternative to the classical Gabriel method. Other silazanes, including hexamethyldisilazane, give lower yields: Synthesis, 150 (1995):

Sanli, D.; Erkey, C. Silylation from supercritical carbon dioxide: a powerful technique for modification of surfaces. J. Mater. Sci. 2015, 50 (22), 7159-7181.

Fainer, N. I.; Kosyakov, V. I. Phase composition of thin silicon carbonitride films obtained by plazma endanced chemical vapor deposition using organosilicon compounds. J. Struct. Chem. 2015, 56 (1), 163-174.

Mentions de danger et de prudence du SGH

Mentions de danger (UE): H225-H314-H318

Highly flammable liquid and vapour. Causes severe skin burns and eye damage. Causes serious eye damage.

Mentions de prudence: P210-P280-P303+P361+P353-P305+P351+P338-P310

Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Wear protective gloves/protective clothing/eye protection/face protection. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER or doctor/physician.

Autres références

Beilstein
741869
Classe de danger
3
Groupe d'emballage
II
Code tarifaire harmonisé
2931.90
TSCA
Yes

Recommandé

Consulté récemment

Produits chimiques

Sciences de la vie

Métaux et matériaux

Catalyseurs

Analytique et matériel de laboratoire