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79-08-3 - Bromoacetic acid, 98+% - A14403 - Alfa Aesar

A14403 Bromoacetic acid, 98+%

Numéro CAS
79-08-3
Synonymes

Dimensions Prix ($) Quantité Disponibilité
250g 32,10
1000g 88,00
5000g 450,00
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Bromoacetic acid, 98+%

MDL
MFCD00002678
EINECS
201-175-8

Propriétés chimiques

Formule
C2H3BrO2
Poids formulaire
138.95
Point de fusion
44-49°
Point d'ébullition
207-209°
Point d'éclair
>110°(230°F)
Densité
1.930
Sensibilité
Light Sensitive & Hygroscopic
Solubilité
Soluble in water, alcohol

Applications

Bromoacetic acid is used in organic synthesis and as an alkylating agent. It is also used as a biochemical for proteomics research. It is an important raw material and intermediate used in organic synthesis, pharmaceuticals, dyes and agrochemicals.

Notes

Store in cool place. Keep container tightly closed in a dry and well-ventilated place. It is hygroscopic in nature and sensitive to light and air. Handle and store under inert gas. Incompatible with strong oxidizing agents and strong bases.

Références bibliographiques

E.A. Barnard.; W.D. Stein. The histidine residue in the active centre of ribonuclease: I. A specific reaction with bromoacetic acid. Journal of Molecular Biology. 1959, 1 (4-5), 339-349.

Philip J. Elving.; Isadore Rosenthal.; Marilyn Koll Kramer. Polarographic Behavior of Organic Compounds. IX. Iodoacetic Acid and the Bromoacetic Acids. J. Am. Chem. Soc. 1951, 73 (4), 1717-1722.

Reaction with a dialkyl phosphite followed by an aldehyde has been used in a convenient one-pot synthesis of acrylic acids: J. Org. Chem., 46, 2514 (1981). For examples with reaction schemes, see Chloroacetic acid, A11482 and 2-Bromopropionic acid, A17569.

Mentions de danger et de prudence du SGH

Mentions de danger (UE): H301-H311-H331-H314-H317

Toxic if swallowed. Toxic in contact with skin. Toxic if inhaled. Causes severe skin burns and eye damage. May cause an allergic skin reaction.

Mentions de prudence: P260u-P280-P301+P310a-P303+P361+P353-P305+P351+P338-P301+P330+P331-P304+P340-P311a-P405-P501a

Wear protective gloves/protective clothing/eye protection/face protection. IF SWALLOWED: IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Rinse mouth. Do NOT induce vomiting. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

Autres références

Merck
14,1400
Beilstein
506167
Classe de danger
8
Groupe d'emballage
II
Code tarifaire harmonisé
2915.90
TSCA
Yes
RTECS
AF5950000

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Catalyseurs

Analytique et matériel de laboratoire