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75-03-6 - Iodoethane, 98+%, stab. with copper - Ethyl iodide - A14444 - Alfa Aesar

A14444 Iodoethane, 98+%, stab. with copper

Numéro CAS
75-03-6
Synonymes
Ethyl iodide

Dimensions Prix ($) Quantité Disponibilité
100g 31,93
500g 111,24
2500g 432,60
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Iodoethane, 98+%, stab. with copper

MDL
MFCD00001091
EINECS
200-833-1

Propriétés chimiques

Formule
CH3CH2I
Poids formulaire
155.97
Point de fusion
-108°
Point d'ébullition
70-73°
Point d'éclair
>73°(163°F)
Densité
1.95
Indice de réfraction
1.5120
Sensibilité
Moisture & Light Sensitive
Solubilité
Miscible with water.

Applications

Iodoethane is an excellent ethylating agent used in organic synthesis to introduce an ethyl group into a compound. It reacts with magnesium to form the Grignard reagent, ethylmagnesium iodide which is used in organic synthesis. It is involved in the preparation of 1-ethyl-3-nitro-2-phenyl-indole and also serves as hydrogen radical promoter.

Notes

Moisture and light sensitive. Keep the container tightly closed in a dry and well-ventilated place. Incompatible with strong bases, strong oxidizing agents and magnesium.

Références bibliographiques

Nijamudheen, A.; Datta, A. Mechanism for C-I Bond Dissociation in Iodoethane, Iodobenzene, and Iodoethene for the C-C Cross Coupling Reactions over Gold Clusters. J. Phys. Chem. C 2013, 117 (41), 21433-21440.

Ljubic, I.; Matasovic, B.; Bonifacic, M. An efficient buffer-mediated control between free radical substitution and proton-coupled electron transfer: dehalogenation of iodoethane by the alpha-hydroxyethyl radical in aqueous solution. Phys. Chem. Chem. Phys. 2013, 15 (41), 18001-18011.

Mentions de danger et de prudence du SGH

Mentions de danger (UE): H334-H315-H319-H317-H302-H335

May cause allergy or asthma symptoms or breathing difficulties if inhaled. Causes skin irritation. Causes serious eye irritation. May cause an allergic skin reaction. Harmful if swallowed. May cause respiratory irritation.

Mentions de prudence: P285-P261-P280-P305+P351+P338-P304+P340-P342+P311-P362-P301+P312-P405-P501a

In case of inadequate ventilation wear respiratory protection. Avoid breathing dust/fume/gas/mist/vapours/spray. Wear protective gloves/protective clothing/eye protection/face protection. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. If experiencing respiratory symptoms: Call a POISON CENTER or doctor/physician. Take off contaminated clothing and wash before reuse. IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

Autres références

Merck
14,3813
Beilstein
505934
Code tarifaire harmonisé
2903.39
TSCA
Yes
RTECS
KI4750000

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Catalyseurs

Analytique et matériel de laboratoire