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497-25-6 - 2-Oxazolidinone, 99% - 2-Oxazolidone - A14543 - Alfa Aesar

A14543 2-Oxazolidinone, 99%

Numéro de CAS
497-25-6
Synonymes
2-Oxazolidone

Conditionnement Prix ($) Quantité Disponibilité
25g 38,70
100g 107,00
500g 364,00
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2-Oxazolidinone, 99%

MDL
MFCD00005268
EINECS
207-840-9

Propriétés chimiques

Formule
C3H5NO2
Poids moleculaire
87.08
Point de fusion
84-89°
Point d'ébullition
220°/48mm
Solubilité
Soluble in water.

Applications

2-Oxazolidinone is used as antimicrobials, in organisms it act as a protein synthesis inhibitors, targeting an early step involving the binding of N-formylmethionyl-tRNA to the ribosome. They are used for chiral synthesis. It has been used as an ethanolamine equivalent, also behaves as an aziridine equivalent as in the conversion of thiophenols or amines to their aminoethyl derivatives.

Notes

Store in cool, dry conditions in a well sealed container. Store away from oxidizing agents.

Références bibliographiques

Hideaki Kakeya; Masayuki Morishita; Hiroyuki Koshino; Tetsu-ichiro Morita; Kimiko Kobayashi and Hiroyuki Osada. Cytoxazone:? A Novel Cytokine Modulator Containing a 2-Oxazolidinone Ring Produced by Streptomyces sp. J. Org. Chem. 1999, 64 (3), 1052-1053.

Guo-Jie Ho; David J. Mathre. Lithium-Initiated Imide Formation. A Simple Method for N-Acylation of 2-Oxazolidinones and Bornane-2,10-Sultam. J. Org. Chem. 1995, 60 (7), 2271-2273.

Has been used as an ethanolamine equivalent, e.g. in reaction with succinic anhydride to give 1-(2-hydroxyethyl)succinimide: Tetrahedron, 44, 261 (1988). Also behaves as an aziridine equivalent as in the conversion of thiophenols or amines to their aminoethyl derivatives: J. Org. Chem., 57, 6257 (1992).

Mentions de danger et de prudence du SGH

Mentions de danger (UE): H315-H319-H335

Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.

Mentions de prudence: P260-P201-P280g-P304+P340-P405-P501a

Do not breathe dust/fume/gas/mist/vapours/spray. Obtain special instructions before use. Wear protective gloves. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

Autres références

Beilstein
106251
Code tarifaire harmonisé
2934.99
TSCA
Yes
RTECS
RQ2450000

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Catalyseurs

Analytique et matériel de laboratoire