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59-88-1 - Phenylhydrazine hydrochloride, 99% - A14645 - Alfa Aesar

A14645 Phenylhydrazine hydrochloride, 99%

Numéro de CAS
59-88-1
Synonymes

Conditionnement Prix ($) Quantité Disponibilité
100g 61,40
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Phenylhydrazine hydrochloride, 99%

MDL
MFCD00012924
EINECS
200-444-7

Propriétés chimiques

Formule
C6H8N2•HCl
Poids moleculaire
144.61
Point de fusion
ca 252° dec.
Solubilité
Soluble in water and alcohol.

Applications

Phenylhydrazine hydrochloride is used as a selective mannosidase inhibitor. It is used in the study of tyrosine phosphorylation of janus protein tyrosine kinase in the EPO-responsive normal erythroblastoid cells of anemic mice. It is used in steroid assays and as an N-protecting reagent. Its free base, phenylhydrazine is used to prepare indoles, which find application as intermediates in the synthesis of various dyes and pharmaceuticals.

Notes

Air and light sensitive. Hygroscopic. Store in cool place. Keep the container tightly closed in a dry and well-ventilated place. Incompatible with strong oxidizing agents and bases.

Références bibliographiques

Butin, A. V.; Uchuskin, M. G.; Pilipenko, A. S.; Serdyuk, O. V.; Trushkov, I. V. Unusual reactivity of beta-(3-indolyl)-alpha, beta-unsaturated ketones. 2-Acetylvinyl group removal by phenylhydrazine hydrochloride. Tetrahedron Lett. 2011, 52 (41), 5255-5258.

Muralirajan, K.; Haridharan, R.; Prakash, S.; Cheng, C. H. Rhodium(III)-Catalyzed in situ Oxidizing Directing Group-Assisted C? H Bond Activation and Olefination: A Route to 2-Vinylanilines. Adv. Synth. Catal. 2015, 357, (4), 761-766.

Mentions de danger et de prudence du SGH

Mentions de danger (UE): H301-H311-H331-H315-H319-H317-H341-H350-H372

Toxic if swallowed. Toxic in contact with skin. Toxic if inhaled. Causes skin irritation. Causes serious eye irritation. May cause an allergic skin reaction. Suspected of causing genetic defects. May cause cancer. Causes damage to organs through prolonged or repeated exposure.

Mentions de prudence: P260-P201-P301+P310a-P305+P351+P338-P405-P501a

Do not breathe dust/fume/gas/mist/vapours/spray. Obtain special instructions before use. IF SWALLOWED: IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

Autres références

Merck
14,7293
Beilstein
3594958
Classe de danger
6.1
Groupe d'emballage
III
Code tarifaire harmonisé
2928.00
TSCA
Yes
RTECS
MV9000000

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Catalyseurs

Analytique et matériel de laboratoire