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102-82-9 - Tri-n-butylamine, 98% - A14868 - Alfa Aesar

A14868 Tri-n-butylamine, 98%

Numéro CAS
102-82-9
Synonymes

Dimensions Prix ($) Quantité Disponibilité
500ml 28,20
2500ml 83,00
10000ml 270,00
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Tri-n-butylamine, 98%

MDL
MFCD00009431
EINECS
203-058-7

Propriétés chimiques

Formule
C12H27N
Poids formulaire
185.36
Point de fusion
<-70°
Point d'ébullition
216°
Point d'éclair
71°(159°F)
Densité
0.778
Indice de réfraction
1.4290
Sensibilité
Hygroscopic
Solubilité
Miscible with acetone, ethanol, ethyl ether and most organic solvents. Immiscible with water.

Applications

Tri-n-butylamine is an important intermediate in the production of phase transfer catalysts like tributylmethylammonium chloride and tributylbenzylammonium chloride. It is also used in pharmaceuticals, agrochemicals, surfactants, lubricant additives, vulcanization accelerators and dyes. It acts as a catalyst and as a solvent in organic syntheses and polymerization reactions. It serves as a strong base anion exchanger, acid acceptor, inhibitor in hydraulic fluids and an emulsifying agent. Further, it is used to prepare photographic chemicals.

Notes

Hygroscopic. Incompatible with strong oxidizing agents.

Références bibliographiques

Nakajima, M.; Fava, E.; Loescher, S.; Jiang, Z.; Rueping, M. Photoredox-Catalyzed Reductive Coupling of Aldehydes, Ketones, and Imines with Visible Light. Angew. Chem. Int. Ed. 2015, 54 (30), 8828-8832.

Sarac, I.; Meier, C. Efficient Automated Solid-Phase Synthesis of DNA and RNA 5'-Triphosphates. Chem. Eur. J. 2015, 21 (46), 16421-16426.

Mentions de danger et de prudence du SGH

Mentions de danger (UE): H310-H330-H302-H315-H319-H227-H401-H411

Fatal in contact with skin. Fatal if inhaled. Harmful if swallowed. Causes skin irritation. Causes serious eye irritation. Combustible liquid. Toxic to aquatic life. Toxic to aquatic life with long lasting effects.

Mentions de prudence: P210-P260-P284-P304+P340-P305+P351+P338-P320-P330-P361-P405-P501a

Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Do not breathe dust/fume/gas/mist/vapours/spray. Wear respiratory protection. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Specific treatment is urgent (see label). Rinse mouth. Remove/Take off immediately all contaminated clothing. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

Autres références

Merck
14,9618
Beilstein
1698872
Classe de danger
6.1
Groupe d'emballage
II
Code tarifaire harmonisé
2921.19
TSCA
Yes
RTECS
YA0350000

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Analytique et matériel de laboratoire