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501-52-0 - 3-Phenylpropionic acid, 99% - Hydrocinnamic acid - A14908 - Alfa Aesar

A14908 3-Phenylpropionic acid, 99%

Numéro CAS
501-52-0
Synonymes
Hydrocinnamic acid

Dimensions Prix ($) Quantité Disponibilité
100g 34,90
500g 134,00
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3-Phenylpropionic acid, 99%

MDL
MFCD00002771
EINECS
207-924-5

Propriétés chimiques

Formule
C6H5(CH2)2CO2H
Poids formulaire
150.18
Point de fusion
47-50°
Point d'ébullition
280°
Point d'éclair
>110°(230°F)
Densité
1.071
Solubilité
Soluble in water

Applications

Hydrocinnamic acid is inhibitor of carboxypeptidase. Hydrocinnamic acid was used in the synthesis of three medium-chain acyl-Coenzyme A?s i.e. 3-phenylpropionyl-CoA from mixed anhydrides of fatty acids.

Notes

Store away from strong oxidizing agents. Keep container tightly closed. Store in cool, dry conditions in well sealed containers.

Références bibliographiques

P. Moesta.; H. Grisebach. l-2-Aminooxy-3-phenylpropionic acid inhibits phytoalexin accumulation in soybean with concomitant loss of resistance against Phytophthora megasperma f. sp. glycinea . Physiological Plant Pathology. 1982, 21, (1), 65-70.

Olivier Ploux.; Manuel Caruso.; Gerard Chassaing.; Andree Marquet. A new modified amino acid. 2-Amino-3-mercapto-3-phenylpropionic acid (3-mercaptophenylalanine). Synthesis of derivatives, separation of stereoisomers, and assignment of absolute configuration. J. Org. Chem. 1988,, 53, (14), 3154-3158.

For the abnormal reaction with thionyl chloride leading to a benzo[b]thiophene derivative, see trans-Cinnamic acid, A13538.

Free radical oxidative cyclization with ɑß-unsaturated nitriles, ketones and esters gives tetrahydronaphthalene derivatives: Tetrahedron Lett., 36, 4307 (1995). For reaction scheme, see Acryl­onitrile, A13058.

Mentions de danger et de prudence du SGH

Mentions de danger (UE): H315-H319-H335

Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.

Mentions de prudence: P261-P280-P305+P351+P338-P304+P340-P362-P312-P321-P405-P403+P233-P501a

Avoid breathing dust/fume/gas/mist/vapours/spray. Wear protective gloves/protective clothing/eye protection/face protection. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Take off contaminated clothing and wash before reuse. Call a POISON CENTER or doctor/physician if you feel unwell. Specific treatment (see label). Store locked up. Store in a well-ventilated place. Keep container tightly closed. Dispose of contents/container in accordance with local/regional/national/international regulations.

Autres références

Merck
14,4784
Beilstein
907515
Code tarifaire harmonisé
2916.39
TSCA
Yes
RTECS
DA8600000

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Catalyseurs

Analytique et matériel de laboratoire