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100-85-6 - Benzyltrimethylammonium hydroxide, 40% w/w in methanol - Triton B - A14927 - Alfa Aesar

A14927 Benzyltrimethylammonium hydroxide, 40% w/w in methanol

Numéro de CAS
100-85-6
Synonymes
Triton B

Conditionnement Prix ($) Quantité Disponibilité
100ml 25,80
500ml 73,80
2500ml 282,00
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Benzyltrimethylammonium hydroxide, 40% w/w in methanol

MDL
MFCD00008281
EINECS
202-895-5

Propriétés chimiques

Formule
C10H17NO
Poids moleculaire
167.25
Point d'ébullition
65°
Point d'éclair
15°(59°F)
Densité
0.920
Indice de réfraction
1.4270
Sensibilité
Air Sensitive
Solubilité
Miscible with water, hydrocarbons, aromatic hydrocarbons and halogenated solvents.

Applications

Benzyltrimethylammonium hydroxide is used as a phase-transfer catalyst. It is also used in aldol condensation reactions and base-catalyzed dehydration reactions. Further, it serves as a strong organic base and used in Horner-Wadsworth-Emmons olefination reactions. In addition, it is an active component in the formulation, which is used in silicon wafer cleaning applications.

Notes

Air Sensitive. Incompatible with strong oxidizing agents.

Références bibliographiques

Triton® is a registered trademark of Rohm and Haas Co.

Useful base catalyst or reagent for many reactions. For use in the Michael addition of nitro-compounds to ɑß-unsaturated esters, see: Org. Synth. Coll., 4, 652 (1963). For C-methylation of 2-Methyl­cyclohexane-1,3-dione, A11218 , see: Org. Synth. Coll., 8, 312 (1993).

Grimaldi, T. B.; Back, D. F.; Zeni, G. Synthesis of Naphthofurans by tBuOK-Catalyzed Intramolecular Anionic Cycloaddition of Unsymmetrical Bis-propargyl Ethers. Eur. J. Org. Chem. 2015, 2015 (31), 6924-6931.

Periyasamy, T.; Asrafali, S. P.; Muthusamy, S. New benzoxazines containing polyhedral oligomeric silsesquioxane from eugenol, guaiacol and vanillin. New J. Chem. 2015, 39 (3), 1691-1702.

Mentions de danger et de prudence du SGH

Mentions de danger (UE): H225-H311-H331-H314-H318-H370

Highly flammable liquid and vapour. Toxic in contact with skin. Toxic if inhaled. Causes severe skin burns and eye damage. Causes serious eye damage. Causes damage to organs.

Mentions de prudence: P210-P260u-P303+P361+P353-P305+P351+P338-P405-P501a

Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Do not breathe dusts or mists. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

Autres références

Beilstein
3917256
Classe de danger
3
Groupe d'emballage
II
Code tarifaire harmonisé
2923.90
TSCA
Yes
RTECS
BO8575000

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