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107-18-6 - Allyl alcohol, 98+% - 2-Propen-1-ol - 3-Hydroxy-1-propene - A15026 - Alfa Aesar

A15026 Allyl alcohol, 98+%

Numéro de CAS
107-18-6
Synonymes
2-Propen-1-ol
3-Hydroxy-1-propene

Conditionnement Prix ($) Quantité Disponibilité
100ml 15,00
500ml 28,20
2500ml 102,00
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Allyl alcohol, 98+%

MDL
MFCD00002920
EINECS
203-470-7

Propriétés chimiques

Formule
C3H6O
Poids moleculaire
58.08
Point de fusion
-129°
Point d'ébullition
95-97°
Point d'éclair
22°(71°F)
Densité
0.852
Indice de réfraction
1.4130
Solubilité
Miscible with water.

Applications

Allyl alcohol is widely used as a precursor to many specialized compounds such as allyl glycidyl ether, allyl diglycidyl carbonate, allyl methacrylate, flame-resistant materials, drying oils and plasticizers. It is used as a raw material for the synthesis of glycerol, glycidyl ethers, esters and amines. It is involved in the synthesis of a variety of polymerizable esters such as diallyl phthalate.

Notes

Incompatible with strong oxidizing agents, acids, oleum and alkali metals. Polymerizes during prolonged storage.

Références bibliographiques

Carboxylic acids can be protected as allyl esters, by reaction of allyl alcohol with an activated carboxyl group. They are readily cleaved in the presence of Pd catalysts: J. Org. Chem., 47, 587 (1982); Angew. Chem. Int. Ed., 23, 71 (1984); J. Chem. Soc., Chem. Commun., 1216 (1990).

Harvey, L.; Sánchez, G.; Kennedy, E. M.; Stockenhuber, M. Enhancing allyl alcohol selectivity in the catalytic conversion of glycerol; influence of product distribution on the subsequent epoxidation step. Asia-Pac. J. Chem. 2015, 10 (4), 598-606.

Fukuda, K.; Tojino, M.; Goto, K.; Dohi, H.; Nishida, Y.; Mizuno, M. A recyclable heavy fluorous tag carrying an allyl alcohol pendant group: design and evaluation toward applications in synthetic carbohydrate chemistry. Carbohydr. Res. 2015, 407, 122-130.

Mentions de danger et de prudence du SGH

Mentions de danger (UE): H225-H301-H311-H331-H315-H319-H335

Highly flammable liquid and vapour. Toxic if swallowed. Toxic in contact with skin. Toxic if inhaled. Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.

Mentions de prudence: P210-P301+P310a-P303+P361+P353-P305+P351+P338-P405-P501a

Keep away from heat/sparks/open flames/hot surfaces. - No smoking. IF SWALLOWED: IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

Autres références

Merck
14,286
Beilstein
605307
Classe de danger
6.1
Groupe d'emballage
I
Code tarifaire harmonisé
2905.29
TSCA
Yes
RTECS
BA5075000

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Catalyseurs

Analytique et matériel de laboratoire