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7440-16-6 - Rhodium, 5% on carbon, dry - A15965 - Alfa Aesar

A15965 Rhodium, 5% on carbon, dry

Numéro CAS
7440-16-6
Synonymes

Dimensions Prix ($) Quantité Disponibilité
1g 50,76
5g 178,20
25g 625,60
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Rhodium, 5% on carbon, dry

MDL
MFCD00011201
EINECS
231-125-0

Propriétés chimiques

Formule
Rh
Solubilité
Insoluble in water.

Applications

Rhodium, 5% on carbon is a useful reagent for the conversation of nitriles to primary amines and the hydrogenation of aromatic rings, pyridines, aldehydes and sugars. It is also used for the reduction of oximes to amines and for the reduction of nitrobenzene to phenylhydroxylamine using hydrazine hydrate as the hydrogen source.

Notes

Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Incompatible with strong oxidizing agents, halogens, chlorine trifluoride and oxygen difluoride.

Références bibliographiques

Joseph J. Mrowca.; Thomas J. Katz. Catalysis of a Cycloaddition Reaction by Rhodium on Carbon. J. Am. Chem. Soc. 1966, 88 (17), 4012-4015 .

Morris Freifelder.; Ralph M. Robinson.; George R. Stone. Hydrogenation of Substituted Pyridines with Rhodium on Carbon Catalyst. J. Org. Chem. 1962, 27 (1), 284-286.

Rhodium catalysts are especially useful for the hydrogenation of aromatic rings under mild conditions. For details for the hydrogenation of 4-aminobenzoic acid to its hexahydro derivative under modest pressure, see: Org. Synth. Coll., 5, 670 (1973).

Rhodium catalysts have also been used for the reduction of oximes to amines.

For a monograph on catalytic hydrogenation, see: P. N. Rylander, Hydrogenation Methods, Academic Press, N.Y. (1985).

For the reduction of nitrobenzene to phenylhydroxylamine using hydrazine hydrate as the hydrogen source, see: Org. Synth. Coll., 8, 16 (1993).

Mentions de danger et de prudence du SGH

Mentions de danger (UE): H228-H315-H319-H335

Flammable solid. Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.

Mentions de prudence: P210-P261-P280-P240-P241-P305+P351+P338-P304+P340-P362-P405-P501a

Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Avoid breathing dust/fume/gas/mist/vapours/spray. Wear protective gloves/protective clothing/eye protection/face protection. Ground/bond container and receiving equipment. Use explosion-proof electrical/ventilating/lighting/ equipment. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Take off contaminated clothing and wash before reuse. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

Autres références

Merck
14,8186
Classe de danger
4.1
Groupe d'emballage
III
Code tarifaire harmonisé
3815.12
TSCA
Yes
RTECS
VI9069000

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