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108-05-4 - Vinyl acetate, 99%, stab. with 8-12ppm hydroquinone - Acetic acid vinyl ester - A16247 - Alfa Aesar

A16247 Vinyl acetate, 99%, stab. with 8-12ppm hydroquinone

Numéro CAS
108-05-4
Synonymes
Acetic acid vinyl ester

Dimensions Prix ($) Quantité Disponibilité
100ml 18,64
500ml 22,05
2500ml 47,28
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Vinyl acetate, 99%, stab. with 8-12ppm hydroquinone

MDL
MFCD00008713
EINECS
203-545-4

Propriétés chimiques

Formule
C4H6O2
Poids formulaire
86.09
Point de fusion
-100°
Point d'ébullition
72-73°
Point d'éclair
-8°(18°F)
Densité
0.932
Indice de réfraction
1.3960
Solubilité
Slightly miscible with water.

Applications

Vinyl acetate is used in the preparation of polyvinyl acetate emulsions and polyvinyl alcohol. It acts as a precursor to polyvinyl acetate. It serves as an ingredient in furniture-glue. It is also used to prepare copolymers with other monomers such as ethylene, acrylic acid. Further, it is used to make adhesives, paints and plastics.

Notes

Light sensitive. Incompatible with acids, bases, oxidizing agents, peroxides, chlorosulfonic acid, ethylene imine, hydrochloric acid, oleum, nitric acid, sulfuric acid and 2-aminoethanol.

Références bibliographiques

For example of mercuric acetate-catalyzed transesterification to long-chain vinyl esters, see: Org. Synth. Coll., 4, 977 (1963).

For thermal [2+2] cycloaddition with chlorotrifluoroethylene, see: Org. Synth. Coll., 5, 235 (1973); and with chlorosulfonyl isocyanate to give a ß-lactam: Org. Synth. Coll., 8, 3 (1993).

Dong, X.; Guan, X.; Jiang, Y.; Ma, J.; Zhang, M. Extension of the TraPPE-UA force field to the simulation of vapor-liquid phase equilibria of vinyl acetate system. J. Mol. Liq. 2015, 209, 520-525.

Belbekhouche, S.; Picton, L.; Le Cerf, D.; Hamaide, T. Pullulan-Based Polymer Surfactants for Vinyl Acetate Miniemulsion Polymerization: Kinetics and Colloidal Stability Investigations. Macromol. Chem. Phys. 2015, 216 (18), 1879-1887.

Mentions de danger et de prudence du SGH

Mentions de danger (UE): H225-H351-H332-H335-H303-H313

Highly flammable liquid and vapour. Suspected of causing cancer. Harmful if inhaled. May cause respiratory irritation. May be harmful if swallowed. May be harmful in contact with skin.

Mentions de prudence: P210-P201-P261-P280-P281-P240-P303+P361+P353-P304+P340-P405-P501a

Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Obtain special instructions before use. Avoid breathing dust/fume/gas/mist/vapours/spray. Wear protective gloves/protective clothing/eye protection/face protection. Use personal protective equipment as required. Ground/bond container and receiving equipment. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

Autres références

Merck
14,9992
Beilstein
1209327
Classe de danger
3
Groupe d'emballage
II
Code tarifaire harmonisé
2915.32
TSCA
Yes
RTECS
AK0875000

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