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766-09-6 - 1-Ethylpiperidine, 99% - N-Ethylpiperidine - A16294 - Alfa Aesar

A16294 1-Ethylpiperidine, 99%

Numéro de CAS
766-09-6
Synonymes
N-Ethylpiperidine

Conditionnement Prix ($) Quantité Disponibilité
500g 101,00
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1-Ethylpiperidine, 99%

MDL
MFCD00006507
EINECS
212-161-6

Propriétés chimiques

Formule
C7H15N
Poids moleculaire
113.20
Point de fusion
-20°
Point d'ébullition
129-131°
Point d'éclair
18°(64°F)
Densité
0.825
Indice de réfraction
1.4440
Solubilité
1-ethylpiperidine salt of benzylpenicillin is considerably less soluble in amyl acetate and acetone.

Applications

In Room temperature phosphorescence of α-bromonaphthalene induced by cyclodextrin in the presence of hexahydropyridine or 1-ethylpiperidine and its application is described. The highest yields of 5-Bromopyrimidine (37%) were obtained by using 1-ethylpiperidine or triethylamine as condensing agent. Tributyltin hydride and 1-ethylpiperidine hypophosphite were mediated intermolecular radical additions to 2, 4, 6-trichlorophenyl vinyl sulfonate.

Notes

Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Store away from strong oxidizing agents.

Références bibliographiques

G. E. Boxer,; P. M. Everett. Colorimetric Determination of Benzylpenicillin. Anal. Chem., 1949, 21 (6), 670-673.

J. F. W. McOmie,; I. M. White .623. Pyrimidines. Part VI. 5-Bromopyrimidine. J. Chem. Soc. 1953, volume 3129-3131.

Hindered, non-nucleophilic base. Preferred base for enantioselective crossed aldol condensations of Sn enolates: Tetrahedron, 40, 1381 (1984). Also found to give excellent results in the formation of anhydrides using Bis(2-oxo-3-oxazolidinyl)­phosphinic chloride, L08775: Synthesis, 616 (1981). Has been used in peptide synthesis via pivaloyl mixed anhydrides: Coll. Czech. Chem. Commun., 27, 1273 (1962).

Mentions de danger et de prudence du SGH

Mentions de danger (UE): H225-H314-H318

Highly flammable liquid and vapour. Causes severe skin burns and eye damage. Causes serious eye damage.

Mentions de prudence: P210-P260u-P303+P361+P353-P305+P351+P338-P405-P501a

Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Do not breathe dusts or mists. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

Autres références

Beilstein
102643
Classe de danger
3
Groupe d'emballage
II
Code tarifaire harmonisé
2933.39
TSCA
Yes
RTECS
TN0250000

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Catalyseurs

Analytique et matériel de laboratoire