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1530-45-6 - (Ethoxycarbonylmethyl)triphenylphosphonium bromide, 98+% - (Carboethoxymethyl)triphenylphosphonium bromide - Ethyl (triphenylphosphonio)acetate bromide - A16347 - Alfa Aesar

A16347 (Ethoxycarbonylmethyl)triphenylphosphonium bromide, 98+%

Numéro CAS
1530-45-6
Synonymes
(Carboethoxymethyl)triphenylphosphonium bromide
Ethyl (triphenylphosphonio)acetate bromide

Dimensions Prix ($) Quantité Disponibilité
25g 31,60
100g 80,80
500g 355,00
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(Ethoxycarbonylmethyl)triphenylphosphonium bromide, 98+%

MDL
MFCD00011835
EINECS
216-230-1

Propriétés chimiques

Formule
CH3CH2O2CCH2P(C6H5)3Br
Poids formulaire
429.30
Point de fusion
ca 150° dec.
Sensibilité
Hygroscopic
Solubilité
It is soluble in water.

Applications

(Ethoxycarbonylmethyl)triphenylphosphonium bromide, is used as a pharmaceutical intermediate.

Notes

Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Keep away from Strong oxidizing agents, Strong bases.

Références bibliographiques

R Alvarez-Sánchez.; D Basketter.; C Pease. Studies of chemical selectivity of hapten, reactivity, and skin sensitization potency. 3. Synthesis and studies on the reactivity toward model nucleophiles of the 13C. Chem. Res. Toxicol. 2003, 16, (5), 627-636.

A Shaabani.; E Soleimani.; HR Khavasi.; RD Hoffmann. An isocyanide-based three-component reaction: synthesis of fully substituted N-alkyl-2-triphenylphosphoranylidene glutarimides. Tetrahedron Letters. 2006, 47, (31), 5493-5496.

For reaction with trifluoroacetic anhydride and triethylamine, followed by pyrolysis as a route to perfluoroalkyl acetylenes, see: Org. Synth. Coll., 9, 436 (1998):

Mentions de danger et de prudence du SGH

Mentions de danger (UE): H315-H319-H335

Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.

Mentions de prudence: P261-P280-P305+P351+P338-P304+P340-P362-P312-P321-P405-P403+P233-P501a

Avoid breathing dust/fume/gas/mist/vapours/spray. Wear protective gloves/protective clothing/eye protection/face protection. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Take off contaminated clothing and wash before reuse. Call a POISON CENTER or doctor/physician if you feel unwell. Specific treatment (see label). Store locked up. Store in a well-ventilated place. Keep container tightly closed. Dispose of contents/container in accordance with local/regional/national/international regulations.

Autres références

Beilstein
3581273
Code tarifaire harmonisé
2931.90
TSCA
No
RTECS
TA2299500

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Consulté récemment

Produits chimiques

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Métaux et matériaux

Catalyseurs

Analytique et matériel de laboratoire