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A17247 Aliquat® 336 TG

Numéro de CAS
63393-96-4
Synonymes
Methyltri-n-octylammonium chloride
Tricaprylylmethylammonium chloride

Stock No. Conditionnement Prix ($) Quantité Disponibilité
A17247-AE 100ml 24,70
A17247-AP 500ml 68,80
A17247-0F 2500ml 260,00
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Aliquat® 336 TG

MDL
MFCD00011862
EINECS
264-120-7

Propriétés chimiques

Formule
[CH3(CH2)7]3NCH3Cl
Poids moleculaire
404.17
Point d'ébullition
>240°
Point d'éclair
132°(269°F)
Densité
0.880
Indice de réfraction
1.4465
Storage & Sensitivity
Hygroscopic. Store under Nitrogen. Ambient temperatures.
Solubilité
Miscible with benzene and chloroform.

Applications

Aliquat 336 is widely utilized as a phase transfer catalyst for the catalytic oxidation of cyclohexene to 1,6-hexanedioic acid. It is involved in the total synthesis of Manzamine A. It serves as an anti-static agent for textile fabrics and carpeting. It finds application in waste water treatment to control foaming. It has a major application as a metal extraction reagent for cadmium, zinc, iron and rare earth metals. It is used as an effective catalyst for the preparation of methylphenyl ether from sodium phenolate with for methyl bromide.

Notes

Incompatible with strong oxidizing agents, acids and bases. BASF have renamed Aliquat 336 to Aliquat 336 TG due to reclassification under GHS / REACh because of the tertiary amine content. There is no change to the product's performance.

Références bibliographiques

Mixture of C8-C10; predominantly C8.

Aliquat is a registered trademark of Cognis Corporation.

Widely used lipophilic phase-transfer catalyst. Catalyzes the synthesis of long-chain alkyl azides from the bromides in water or formamide: Tetrahedron Lett., 30, 1245 (1989), the formation and saponification of hindered esters with KOH in the absence of solvent: J. Org. Chem., 51, 740 (1986), the solvent-free SNAr reactions of halopyridines: Heterocycles, 32, 1947 (1991), and dehydrohalogenation of vic-dibromides to alkynes: Org. Prep. Proced. Int., 21, 232 (1989). Catalyzes the solvent-free liquid-liquid phase-transfer hydroboration of olefins, using aqueous NaBH4: Synlett, 997 (2000). See Appendix 2.

Yokokita, T.; Kasamatsu, Y.; Yoshimura, T.; Takahashi, N.; Shinohara, A. Distribution Behavior of Nb, Ta, and Pa as Homologues of Db in Cation Exchange and Solid-Liquid and Liquid-Liquid Extractions by Aliquat 336 from Hydrochloric Acid. Solvent Extr. Ion Exch. 2015, 33 (5), 472-495.

Zhao, J.; Hu, Q.; Li, Y.; Liu, H. Efficient separation of vanadium from chromium by a novel ionic liquid-based synergistic extraction strategy. Chem. Eng. J. 2015, 264, 487-495.

Mentions de danger et de prudence du SGH

Mentions de danger (UE): H301-H314-H335-H360FD-H373

Toxic if swallowed. Causes severe skin burns and eye damage. May cause respiratory irritation. May damage fertility. Suspected of damaging the unborn child. May damage fertility. May damage the unborn child. May cause damage to organs through prolonged or repeated exposure.

Mentions de prudence: P201-P202-P260-P264b-P270-P271-P281-P303+P361+P353-P304+P340-P305+P351+P338-P310-P330-P331-P363-P501c

Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Do not breathe dust/fume/gas/mist/vapours/spray. Wash face, hands and any exposed skin thoroughly after handling Do not eat, drink or smoke when using this product. Use only outdoors or in a well-ventilated area. Use personal protective equipment as required. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER or doctor/physician. Rinse mouth. Do NOT induce vomiting. Wash contaminated clothing before reuse. Dispose of contents/ container to an approved waste disposal plant

Autres références

Classe de danger
8
Groupe d'emballage
III
Code tarifaire harmonisé
2923.90
TSCA
Yes
RTECS
BR8575000

Recommandé

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