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1148-79-4 - 2,2':6',2''-Terpyridine, 97% - 2,6-Bis(2-pyridyl)pyridine - A17750 - Alfa Aesar

A17750 2,2':6',2''-Terpyridine, 97%

Numéro CAS
1148-79-4
Synonymes
2,6-Bis(2-pyridyl)pyridine

Dimensions Prix ($) Quantité Disponibilité
0.25g 39,51
1g 109,97
5g 391,40
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2,2':6',2''-Terpyridine, 97%

MDL
MFCD00006213
EINECS
214-559-5

Propriétés chimiques

Formule
C15H11N3
Poids formulaire
233.28
Point de fusion
89-92°
Solubilité
Soluble in most organic solvents.

Applications

2,2';6',2"-terpyridine is widely utilized in the field of supramolecular chemistry, which is used to manufacture the racks, ladders and grids, helicates, catenanes and dendrimers. It plays an important role as a ligand in coordination chemistry. Its complexes are employed in the oxidation of alcohols, the carbonylation of aromatic compounds and as oxygen-binding molecules. Functionalized terpyridine ligands were used in semiconductors and solar panels. It forms chealate complexes with europium(III) and terbium(III), which is used in protein labelling.

Notes

Keep container tightly closed in a dry and well-ventilated place. Incompatible with strong oxidizing agents.

Références bibliographiques

Schönle, J.; Constable, E. C.; Housecroft, C. E.; Prescimone, A.; Zampese, J. E. Homoleptic and heteroleptic complexes of chromium(III) containing 4'-diphenylamino-2,2':6',2?-terpyridine ligands. Polyhedron 2015, 89 182-188.

Harper, B. W. J.; Aldrich-Wright, J. R. The synthesis, characterisation and cytotoxicity of bisintercalating (2,2':6',2''-terpyridine)platinum(II) complexes. Dalton Trans. 2015, 44 (1), 87-96.

Mentions de danger et de prudence du SGH

Mentions de danger (UE): H300-H310-H315-H319-H335

Fatal if swallowed. Fatal in contact with skin. Causes skin irritation. Causes serious eye irritation. May cause respiratory irritation.

Mentions de prudence: P261-P262-P280-P301+P310-P305+P351+P338-P361-P302+P350-P304+P340-P405-P501a

Avoid breathing dust/fume/gas/mist/vapours/spray. Do not get in eyes, on skin, or on clothing. Wear protective gloves/protective clothing/eye protection/face protection. IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Remove/Take off immediately all contaminated clothing. IF ON SKIN: Gently wash with plenty of soap and water. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

Autres références

Classe de danger
6.1
Groupe d'emballage
I
Code tarifaire harmonisé
2933.39
TSCA
Yes

Recommandé

  • L01190

    2,2'-Bipyrimidine, 96%
  • L14728

    4'-Chloro-2,2':6',2''-terpyridine, 98%
  • 11043

    Ruthenium(III) chloride hydrate, 99.9% (PGM basis), Ru 38% min
  • 11495

    Ammonium hexafluorophosphate, 99.5%
  • 30569

    2,2'-Bipyridine, ACS, 98%

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