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124-02-7 - Diallylamine, 98% - A18950 - Alfa Aesar

A18950 Diallylamine, 98%

Numéro CAS
124-02-7
Synonymes

Dimensions Prix ($) Quantité Disponibilité
100ml 27,09
500ml 46,40
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Diallylamine, 98%

MDL
MFCD00008642
EINECS
204-671-2

Propriétés chimiques

Formule
(CH2=CHCH2)2NH
Poids formulaire
97.16
Point de fusion
-88°
Point d'ébullition
111-112°
Point d'éclair
7°(44°F)
Densité
0.789
Indice de réfraction
1.4405
Sensibilité
Air Sensitive
Solubilité
Soluble in ethanol and ether. Moderately soluble in water.

Applications

Diallylamine is used as an intermediate for ion exchange resins, pharmaceuticals, water soluble polymers, rubber chemicals, polymerization initiators and cross-linking agents.

Notes

Air Sensitive. store away from water/moisture and air. Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Store away from oxidizing agent.

Références bibliographiques

Florence Garro-Helion; Ahmed Merzouk; Francois Guibe. Mild and selective palladium(0)-catalyzed deallylation of allylic amines. Allylamine and diallylamine as very convenient ammonia equivalents for the synthesis of primary amines. J. Org. Chem., 1993, 58 (22), 6109-6113.

Susumu Harada; and Masamichi Katayama. The cyclo-copolymerization of diallyl compound and sulfur dioxide. I. Diallylamine hydrochloride and sulfur dioxide. Journal of Bacteriology, 1966, 90(1), 177-186.

Pd catalyzed coupling with aryl or heteroaryl halides followed by cleavage with methanesulfonic acid or BF3 etherate in the presence of Pd on carbon, provides a mild route to aryl or heteroaryl amines in which the diallylamine behaves as an ammonia equivalent: Tetrahedron Lett., 39, 1313 (1998).

Mentions de danger et de prudence du SGH

Mentions de danger (UE): H225-H311-H330-H302-H314-H318

Highly flammable liquid and vapour. Toxic in contact with skin. Fatal if inhaled. Harmful if swallowed. Causes severe skin burns and eye damage. Causes serious eye damage.

Mentions de prudence: P210-P260-P303+P361+P353-P304+P340-P305+P351+P338-P320-P330-P361-P405-P501a

Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Do not breathe dust/fume/gas/mist/vapours/spray. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. IF INHALED: Remove to fresh air and keep at rest in a position comfortable for breathing. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Specific treatment is urgent (see label). Rinse mouth. Store locked up. Dispose of contents/container in accordance with local/regional/national/international regulations.

Autres références

Merck
14,2971
Beilstein
773718
Classe de danger
3
Groupe d'emballage
II
Code tarifaire harmonisé
2921.19
TSCA
Yes
RTECS
UC6650000

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Catalyseurs

Analytique et matériel de laboratoire